Volume 57, Issue 9 pp. i75-i76

Pentaammine­nitro­syl­chromium(III) dichloride

First published: 03 August 2004
Haruo Akashi, e-mail: [email protected]

Abstract

The cation in the title compound, [Cr(NO)(NH3)5]Cl2, is distorted octahedral with a linear Cr—N—O moiety. The short Cr—N(nitro­syl) distance of 1.692 (7) Å indicates significant multiple bonding between these atoms. The Cr atom, the NO group and the N atom trans to NO have m2m symmetry and the remaining N and Cl atoms have m symmetry.

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