Volume 65, Issue 12 pp. o612-o614

Two novel bis-azomethines derived from quinoxaline-2-carbaldehyde

Digna Varghese

Digna Varghese

Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, Kerala, India

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V. Arun

V. Arun

Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, Kerala, India

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P. P. Robinson

P. P. Robinson

Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, Kerala, India

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Manju Sebastian

Manju Sebastian

Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, Kerala, India

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P. Leeju

P. Leeju

Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, Kerala, India

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G. Varsha

G. Varsha

Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, Kerala, India

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K. K. M. Yusuff

K. K. M. Yusuff

Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, Kerala, India

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First published: 07 December 2009
K. K. M. Yusuff, e-mail: [email protected].

Abstract

The Schiff base compounds N,N′-bis[(E)-quinoxalin-2-ylmethylidene]propane-1,3-diamine, C21H18N6, (I), and N,N′-bis[(E)-quinoxalin-2-ylmethylidene]butane-1,4-diamine, C22H20N6, (II), crystallize in the monoclinic crystal system. These molecules have crystallographically imposed symmetry. Compound (I) is located on a crystallographic twofold axis and (II) is located on an inversion centre. The molecular conformations of these crystal structures are stabilized by aromatic π–π stacking interactions.

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