Volume 60, Issue 8 pp. m363-m365

catena-Poly[[diaquabis(2-chloronicotinato-κ2O,O′)cadmium(II)]-μ-2-chloronicotinato-κ3O,O′:N]

First published: 05 August 2004
Citations: 1
Shan Gao, e-mail: [email protected]

Abstract

In the title neutral coordination polymer, [Cd(C6H3ClNO2)2(H2O)2]n, each CdII ion is coordinated by one N and four O atoms from three 2-chloro­nicotinate ligands and by two aqua ligands, defining a distorted monocapped octahedral coordination geometry. Adjacent Cd atoms are linked by the pyridyl N atom and the bidentate carboxyl­ate functional group of a 2-­chloro­nicotinate ligand, forming a one-dimensional infinite chain along the b axis. The Cd⋯Cd distance is 8.112 (3) Å. These chains are linked by O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional network structure.

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