Volume 59, Issue 10 pp. o601-o602

2-[(2-Hydro­xy-4-nitro­phenyl)­amino­methyl­ene]­cyclo­hexa-3,5-dien-1(2H)-one

First published: 09 June 2004
Citations: 2
Cem Cüneyt Ersanlı, e-mail: [email protected]

Abstract

The title compound, C13H10N2O4, adopts the keto–amine tautomeric form and displays an intramolecular N—H⋯O [N⋯O = 2.579 (2) Å] and three intermolecular O—H⋯O [O⋯O = 2.561 (2) Å] and C—H⋯O [C⋯O = 3.274 (2) and 3.318 (2) Å] hydrogen bonds. The keto–amine structure is favoured by through-mol­ecule conjugation between the hydroxy O atom and imine N atom. The dihedral angle between the planes of the two aromatic rings is 10.79 (4)°.

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