Volume 59, Issue 10 pp. m405-m406

Tetra-μ-chloro-1:2κ4Cl;1:3κ4Cl-bis(4,4′-di­methyl-2,2′-bi­pyridine)-2κ2N,3κ2N-lithium(I)­dipalladium(II) tetrakis­(penta­fluoro­phenyl)­borate di­chloro­methane 1.196-solvate

First published: 09 June 2004
Han Shen, e-mail: [email protected]

Abstract

In the crystal structure of the title compound, [LiPd2Cl4(C12H12N2)2](C24F20B)·1.196CD2Cl2 or [{(Me2bipy)PdCl2}2(μ-Li)]+·B(C6F5)4·1.196CD2Cl2 (Me2bipy is 4,4′-di­methyl-2,2′-bi­pyridine), an Li+ cation is stabilized by complexation with two (Me2bipy)PdCl2 units through weak Li—Cl interactions. This compound is thus a rare example of a complex that exhibits an arrested Cl abstraction.

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