Tetra-μ-chloro-1:2κ4Cl;1:3κ4Cl-bis(4,4′-dimethyl-2,2′-bipyridine)-2κ2N,3κ2N-lithium(I)dipalladium(II) tetrakis(pentafluorophenyl)borate dichloromethane 1.196-solvate
Abstract
In the crystal structure of the title compound, [LiPd2Cl4(C12H12N2)2](C24F20B)·1.196CD2Cl2 or [{(Me2bipy)PdCl2}2(μ-Li)]+·B(C6F5)4−·1.196CD2Cl2 (Me2bipy is 4,4′-dimethyl-2,2′-bipyridine), an Li+ cation is stabilized by complexation with two (Me2bipy)PdCl2 units through weak Li—Cl interactions. This compound is thus a rare example of a complex that exhibits an arrested Cl− abstraction.