Volume 59, Issue 10 pp. m390-m391

Tris­[di­phenyl(2-pyridyl)­phosphine]-μ3-iodo-tri-μ3-sulfido-sulfidotrisilvertungsten di­chloro­methane hemisolvate

First published: 09 June 2004
He-Gen Zheng, e-mail: [email protected]

Abstract

The title compound, [Ag3WIS4(C17H14NP)3]·0.5CH2Cl2, is a cubane-type heterometallic cluster containing di­phenyl(2-pyridyl)­phosphine (Ph2PPy). The pyridyl group of Ph2PPy remains uncoordinated, so the Ph2PPy ligand is monodentate and coordinates to one Ag atom. The W atom and three Ag atoms form a distorted tetrahedral geometry, capped by one I atom and three S atoms.

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