Volume 59, Issue 10 pp. m402-m404

catena-Poly­[[[(1,10-phenanthroline-κ2N,N′)­manganese(II)]-μ-l-tartrato-κ4O1,O2:O3,O4] hexahydrate]

First published: 09 June 2004
Qiutian Liu, e-mail: [email protected]

Abstract

The title compound, {[Mn(C4H4O6)(C12H8N2)]·6H2O}n, has a linear chain structure containing monomeric [Mn(C4H4O6)(C12H8N2)] repeat units. Each manganese ion is six-coordinate, with the two phenanthroline N atoms [Mn—N = 2.229 (2) and 2.235 (2) Å] and four O atoms from two tartrate anions [Mn—OCOO = 2.1252 (19) and 2.1310 (19) Å, and Mn—OOH = 2.2404 (19) and 2.2424 (19) Å] forming a seriously distorted octahedral coordination environment. Six water mol­ecules exist outside every repeat unit as solvate mol­ecules. Extensive hydrogen-bonding interactions and π–π stacking of the phenanthroline moieties exist between the chains.

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