Volume 56, Issue 6 pp. e257-e258

Di­methyl­phenyl­sulfonium tri­fluoro­methane­sulfonate and methyl­di­phenyl­sulfonium tri­fluoro­methane­sulfonate

Kerstin Schulze-Matthäi

Kerstin Schulze-Matthäi

Institut für Chemie, Humboldt-Universität zu Berlin, Hessische Strasse 1-2, 10115 Berlin, Germany

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Jürgen Bendig

Jürgen Bendig

Institut für Chemie, Humboldt-Universität zu Berlin, Hessische Strasse 1-2, 10115 Berlin, Germany

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Petra Neubauer

Petra Neubauer

Institut für Chemie, Humboldt-Universität zu Berlin, Hessische Strasse 1-2, 10115 Berlin, Germany

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Burkhard Ziemer

Burkhard Ziemer

Institut für Chemie, Humboldt-Universität zu Berlin, Hessische Strasse 1-2, 10115 Berlin, Germany

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First published: 30 June 2004
Citations: 1
Burkhard Ziemer, e-mail: [email protected]

Abstract

The bonding geometry of sulfur in the cations of the title compounds, C8H11S+·CF3SO3 and C13H13S+·CF3SO3, respectively, is similar and is independent of the ratio of the Me/Ph substituents. As expected, in both cations, the S—Ph bonds are somewhat shorter than the S—Me bonds. In both crystal structures, the interaction between cations and anions is similar.

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