Volume 56, Issue 6 pp. 627-628

Lanthanum selenite, La2(SeO3)3

William T. A. Harrison

William T. A. Harrison

Department of Chemistry, University of Aberdeen, Aberdeen AB24 3UE, Scotland

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First published: 30 June 2004
Citations: 11
William T. A. Harrison, e-mail: [email protected]

Abstract

Hydro­thermally prepared La2(SeO3)3 contains a three-dimensional network of LaO10 polyhedra [dav(La—O) = 2.622 (3) Å] and SeO3 pyramids [dav(Se—O) = 1.691 (3) Å]. One of the SeO3 pyramids is in a general position and the other has crystallographic m symmetry. There are pseudo-channels in the [010] direction which are probably associated with the SeIV lone pairs.

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