Volume 56, Issue 6 pp. 672-673

1,4,4-Tri­methyl-9-phenyl-8-oxa-9-aza­bi­cyclo­[3.2.2]­non-6-en-2-one

First published: 30 June 2004
Alvaro W. Mombrú, e-mail: [email protected]

Abstract

The structure of the adduct of eucarvone with nitro­so­benzene, C16H19NO2, is reported. The [3.2.2] bicyclic system corresponds to two seven-membered rings in boat and distorted chair conformations and a six-membered ring that adopts a distorted boat conformation. No conjugation is observed between the phenyl group and the N—O system. The packing is directed mainly by a C⋯O hydrogen bond, C—H⋯O-(1 − x, −y, z) and by intermolecular C—H⋯π interactions.

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