Volume 56, Issue 6 pp. 633-634

6-Hexamethylbenzene)(mesidine)­ditriflatoruthenium(II)

Frank J. Feher

Frank J. Feher

Chemistry Department, University of California at Irvine, Irvine, CA 92697-2025, USA

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Richard K. Baldwin

Richard K. Baldwin

Chemistry Department, University of California at Irvine, Irvine, CA 92697-2025, USA

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Joseph W. Ziller

Joseph W. Ziller

Chemistry Department, University of California at Irvine, Irvine, CA 92697-2025, USA

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First published: 30 June 2004
Frank J. Feher, e-mail: [email protected]

Abstract

The crystal structure of the title complex, (η6-hexamethylbenzene)bis(trifluoromethanesulfonato-O)(2,4,6-trimethylanil­ine-N)ruthenium(II), [Ru(CF3O3S)2(C12H18)(C9H13N)], is described. The complex has the classic three-legged piano-stool structure with a planar arene 1.667 Å from the metal, two monodentate O-bound tri­fluoro­methane­sulfonate ligands [Ru—O 2.169 (2) and 2.174 (2) Å] and one N-bound mesidine ligand [Ru—N 2.198 (2) Å]. The Ru—N distance is relatively long and the average Ru—O distance is relatively short when compared with previously characterized RuII complexes.

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