Research Article

Probing Photo-Assisted Charge Storage Mechanism Using Bi-Fe Perovskite Oxide Electrode for Solar Supercapacitor

Manopriya Samtham

orcid.org/0000-0003-0685-0156

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

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Ajay Patil,

Ajay Patil

orcid.org/0009-0004-7052-9054

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

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Ekta Choudhary,

Ekta Choudhary

orcid.org/0000-0003-0054-3323

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

Department of Physics, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

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Himanshu Srivastava,

Himanshu Srivastava

Accelerator Physics and Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore, 452013 India

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Ravindra Jangir,

Ravindra Jangir

orcid.org/0000-0003-2856-4388

Accelerator Physics and Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore, 452013 India

Homi Bhabha National Institute, BARC Training School Complex, Anushaktinagar, Mumbai, 400094 India

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Ram J. Choudhary,

Corresponding Author

Ram J. Choudhary

[email protected]

orcid.org/0000-0003-0029-1541

UGC-DAE Consortium for Scientific Research (CSR) University Campus, Khandwa Road, Indore, 452001 India

E-mail: [email protected]; [email protected]

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Rupesh S. Devan,

Corresponding Author

Rupesh S. Devan

[email protected]

orcid.org/0000-0001-9550-7506

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

Centre for Electric Vehicle & Intelligent Transport System, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

Multidisciplinary Academic Research Centre, National Dong Hwa University, Hualien, 974301 Taiwan

E-mail: [email protected]; [email protected]

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Manopriya Samtham,

Manopriya Samtham

orcid.org/0000-0003-0685-0156

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

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Ajay Patil,

Ajay Patil

orcid.org/0009-0004-7052-9054

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

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Ekta Choudhary,

Ekta Choudhary

orcid.org/0000-0003-0054-3323

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

Department of Physics, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

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Himanshu Srivastava,

Himanshu Srivastava

Accelerator Physics and Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore, 452013 India

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Ravindra Jangir,

Ravindra Jangir

orcid.org/0000-0003-2856-4388

Accelerator Physics and Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore, 452013 India

Homi Bhabha National Institute, BARC Training School Complex, Anushaktinagar, Mumbai, 400094 India

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Ram J. Choudhary,

Corresponding Author

Ram J. Choudhary

[email protected]

orcid.org/0000-0003-0029-1541

UGC-DAE Consortium for Scientific Research (CSR) University Campus, Khandwa Road, Indore, 452001 India

E-mail: [email protected]; [email protected]

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Rupesh S. Devan,

Corresponding Author

Rupesh S. Devan

[email protected]

orcid.org/0000-0001-9550-7506

Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

Centre for Electric Vehicle & Intelligent Transport System, Indian Institute of Technology Indore, Simrol, Indore, 453552 India

Multidisciplinary Academic Research Centre, National Dong Hwa University, Hualien, 974301 Taiwan

E-mail: [email protected]; [email protected]

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First published: 23 December 2024

https://doi.org/10.1002/smtd.202401441

Citations: 2

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Abstract

In this study, the rhombohedral crystalline pure phase BiFeO₃ (BFO) of irregularly shaped spherical particles of ≈100 nm and energy bandgap of ≈2.31 eV are synthesized by sol–gel auto-combustion method and explored as electrode material for photo-assisted supercapacitor. The electronic structure studies revealed that the coexistence of heterovalent Bi and Fe elements accelerated the electrochemical redox kinetics and photo-assisted charge storage properties. The resonant photoemission studies confirmed that near the Fermi level, the valence band spectra comprised the Fe3d and O2p hybridized states. The Fe-O hybridized state felicitates the charge transfer transitions (O2p (h⁺) + hυ ↔ Fe³⁺ + e⁻ ↔ Fe²⁺), which assists the intercalation/de-intercalation process of OH⁻ anions. Therefore, BFO has delivered 26.77% photo efficiency and the enhanced specific capacity of 21 Cg⁻¹ at 2 Ag⁻¹ in aq. 3m KOH under illumination, which is attributed to the accelerated photo-generated charge carrier separation and storage with surface polarization effect. BFO also delivered capacitance retention of 77.5% even after 1000 continuous GCD cycles under visible light irradiation.

Conflict of Interest

The authors declare no conflict of interest.

Supporting Information

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Volume9, Issue4

April 22, 2025

2401441

Probing Photo-Assisted Charge Storage Mechanism Using Bi-Fe Perovskite Oxide Electrode for Solar Supercapacitor

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Probing Photo-Assisted Charge Storage Mechanism Using Bi-Fe Perovskite Oxide Electrode for Solar Supercapacitor

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Supporting Information

References

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