Biomimetic Multi-Interface Design of Raspberry-like Absorbent: Gd-doped FeNi3@Covalent Organic Framework Derivatives for Efficient Electromagnetic Attenuation
Ruizhe Hu
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorXue He
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorYuqi Luo
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorCorresponding Author
Chongbo Liu
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorShiyu Liu
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorXintong Lv
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorJinxi Yan
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorCorresponding Author
Yuhui Peng
Key Laboratory of Nondestructive Testing, Ministry of Education, School of Instrument Science and Optoelectronic Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorMingyue Yuan
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Academy for Engineering & Technology, Fudan University, Shanghai, 200438 P. R. China
Search for more papers by this authorCorresponding Author
Renchao Che
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Academy for Engineering & Technology, Fudan University, Shanghai, 200438 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorRuizhe Hu
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorXue He
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorYuqi Luo
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorCorresponding Author
Chongbo Liu
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorShiyu Liu
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorXintong Lv
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorJinxi Yan
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
Search for more papers by this authorCorresponding Author
Yuhui Peng
Key Laboratory of Nondestructive Testing, Ministry of Education, School of Instrument Science and Optoelectronic Engineering, Nanchang Hangkong University, Nanchang, 330063 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorMingyue Yuan
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Academy for Engineering & Technology, Fudan University, Shanghai, 200438 P. R. China
Search for more papers by this authorCorresponding Author
Renchao Che
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Academy for Engineering & Technology, Fudan University, Shanghai, 200438 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
Structural design and interface regulation are useful strategies for achieving strong electromagnetic wave absorption (EMWA) and broad effective absorption bandwidth (EAB). Herein, a monomer-mediated strategy is employed to control the growth of covalent organic framework (COF) wrapping flower-shaped Gd-doped FeNi3 (GFN), and a novel raspberry-like absorbent based on biomimetic design is fabricated by thermal catalysis. Further, a unique dielectric-magnetic synergistic system is constructed by utilizing the COF-derived nitrogen-doped porous carbon (NPC) as the shell and anisotropic GFN as the core. The electromagnetic parameters of the GFN@NPC composites can be tuned by adjusting the proportions of GFN and NPC. Off-axis electron holography results further clarify the interface polarization and microscale magnetic interactions affecting the EMW loss mechanism. As a result, the GFN@NPC samples exhibit broad EMWA performance. The EAB values of all GFN@NPC composites reach up to 6.0 GHz, with the GFN@NPC-2 sample showing a minimum reflection loss (RLmin) of −69.6 dB at 1.68 mm. In addition, GFN@NPC-2 achieves a maximum radar cross–section (RCS) reduction of 29.75 dB·m2. A multi-layer gradient structure is also constructed using metamaterial simulation to achieve an ultra-wide EAB of 12.24 GHz. Overall, this work provides a novel bio-inspired design strategy to develop high-performance EMWA materials.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
Supporting Information
| Filename | Description |
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| smtd202401299-sup-0001-SuppMat.pdf1.3 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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