Unveiling Aqueous Potassium-Ion Batteries with Prussian Blue Analogue Cathodes
Xu Tan
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorChenyang Gao
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZhifen Luo
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorWeijia Fan
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorXiaosong Xiong
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZezhong Shi
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorNingxun Zhang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZheng Yang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorYuan Ma
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorXin-Bing Cheng
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorYiren Zhong
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorJiarui He
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZhi Zhu
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorFaxing Wang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorCorresponding Author
Tao Wang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorBingan Lu
School of Physics and Electronics, Hunan University, Changsha, 410082 P. R. China
Search for more papers by this authorCorresponding Author
Yuping Wu
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorXu Tan
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorChenyang Gao
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZhifen Luo
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorWeijia Fan
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorXiaosong Xiong
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZezhong Shi
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorNingxun Zhang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZheng Yang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorYuan Ma
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorXin-Bing Cheng
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorYiren Zhong
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorJiarui He
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorZhi Zhu
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorFaxing Wang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
Search for more papers by this authorCorresponding Author
Tao Wang
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorBingan Lu
School of Physics and Electronics, Hunan University, Changsha, 410082 P. R. China
Search for more papers by this authorCorresponding Author
Yuping Wu
Confucius Energy Storage Lab, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Z Energy Storage Center & School of Energy and Environment, Southeast University, Nanjing, 211189 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorAbstract
Aqueous rechargeable potassium-ion batteries have considerable advantages and potentials in the application of large-scale energy storage systems, owing to its high safety, abundant potassium resources, and environmental friendliness. However, the practical applications are fraught with numerous challenges. Identification of suitable cathode materials and potassium storage mechanisms are of great significance. Herein, an aqueous potassium-ion battery comprising Prussian blue analogs cathode (K1.15Fe[Fe(CN)6]·1.36H2O) and perylene-3,4,9,10-tetracarboxylic anode is designed, which delivers a high energy density of 52.0 Wh kg−1 and excellent cycling stability with high capacity retention of 84.5% after 4000 cycles. Importantly, a synergistic study of the relationships among crystal structure, spin state, kinetics, and electrochemical performances is thoroughly conducted. By employing in situ and ex situ characterizations, the potassium storage mechanism is comprehensively elucidated from multiple perspectives.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| smll202410350-sup-0001-SuppMat.docx2.7 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1Z. Liu, Y. Huang, Y. Huang, Q. Yang, X. Li, Z. Huang, C. Zhi, Chem. Soc. Rev. 2020, 49, 180.
- 2J. Ge, L. Fan, A. M. Rao, J. Zhou, B. Lu, Nat. Sustain. 2021, 5, 225.
- 3T. Hosaka, K. Kubota, A. S. Hameed, S. Komaba, Chem. Rev. 2020, 120, 6358.
- 4T. Wang, Z. Shi, F. Wang, J. He, Y. Zhong, Y. Ma, Z. Zhu, X.-B. Cheng, K. I. Ozoemena, Y. Wu, EES Catal. 2024, 2, 696.
- 5T. Wang, Z. Shi, Y. Zhong, Y. Ma, J. He, Z. Zhu, X. B. Cheng, B. Lu, Y. Wu, Small 2024, 2310907.
- 6S. Chong, T. Li, S. Qiao, Y.-C. Yang, Z. Liu, J. Yang, H.-Y. Tuan, G. Cao, W. Huang, ACS Nano 2024, 18, 3801.
- 7W. Shu, J. Li, G. Zhang, J. Meng, X. Wang, L. Mai, Nano-Micro Lett. 2024, 16, 128.
- 8S. Qiao, Q. Zhou, H. K. Liu, S. X. Dou, S. Chong, Nano Lett. 2024, 24, 15167.
- 9Q. Zhou, H. K. Liu, S. X. Dou, S. Chong, ACS Nano 2024, 18, 7287.
- 10L. Jiang, Y. Lu, C. Zhao, L. Liu, J. Zhang, Q. Zhang, X. Shen, J. Zhao, X. Yu, H. Li, X. Huang, L. Chen, Y.-S. Hu, Nat. Energy 2019, 4, 495.
- 11G. Xie, X. Tan, Z. Shi, Y. Peng, Y. Ma, Y. Zhong, F. Wang, J. He, Z. Zhu, X. B. Cheng, G. Wang, T. Wang, Y. Wu, Adv. Funct. Mater. 2024, 2414714.
- 12F. Sagane, T. Abe, Y. Iriyama, Z. Ogumi, J. Power Sources 2005, 146, 749.
- 13K. Kubota, M. Dahbi, T. Hosaka, S. Kumakura, S. Komaba, Chem. Rec. 2018, 18, 459.
- 14X. Zhang, T. Xiong, B. He, S. Feng, X. Wang, L. Wei, L. Mai, Energy Environ. Sci. 2022, 15, 3750.
- 15Y. Mo, W. Zhou, K. Wang, K. Xiao, Y. Chen, Z. Wang, P. Tang, P. Xiao, Y. Gong, S. Chen, P. Gao, J. Liu, ACS Energy Lett. 2023, 8, 995.
- 16L. Jiang, Y.-C. Lu, ACS Energy Lett. 2024, 9, 985.
- 17D. Su, A. McDonagh, S. Z. Qiao, G. Wang, Adv. Mater. 2017, 29, 1604007.
- 18M. Ma, K. Yao, Y. Wang, D. Fattakhova-Rohlfing, S. Chong, Adv. Funct. Mater. 2024, 34, 2315662.
- 19S. Zhao, Z. Guo, K. Yan, X. Guo, S. Wan, F. He, B. Sun, G. Wang, Small Struct. 2020, 2, 2000054.
- 20X. Zhang, J. Meng, X. Wang, Z. Xiao, P. Wu, L. Mai, Energy Storage Mater. 2021, 38, 30.
- 21Z. Wang, W. Zhuo, J. Li, L. Ma, S. Tan, G. Zhang, H. Yin, W. Qin, H. Wang, L. Pan, A. Qin, W. Mai, Nano Energy 2022, 98, 107243.
- 22G.-H. Lee, Y. Seon Kim, D.-W. Kim, Chem. Eng. J. 2020, 388, 124294.
- 23M. Wang, H. Wang, H. Zhang, X. Li, J. Energy Chem. 2020, 48, 14.
- 24Y. Lu, L. Wang, J. Cheng, J. B. Goodenough, Chem. Commun. 2012, 48, 6544.
- 25M. Jiang, Z. Hou, J. Wang, L. Ren, Y. Zhang, J.-G. Wang, Nano Energy 2022, 102, 107708.
- 26C. Xia, J. Guo, P. Li, X. Zhang, H. N. Alshareef, Angew. Chem. 2018, 57, 3943.
- 27C. Li, W. Wu, S. Zhang, L. He, Y. Zhu, J. Wang, L. Fu, Y. Chen, Y. Wu, W. Huang, J. Mater. Chem. A 2019, 7, 4110.
- 28M. Xia, X. Zhang, T. Liu, H. Yu, S. Chen, N. Peng, R. Zheng, J. Zhang, J. Shu, Chem. Eng. J. 2020, 394, 124923.
- 29K. Lu, H. Zhang, S. Gao, Y. Cheng, H. Ma, Nanoscale 2018, 10, 20754.
- 30W. Ren, X. Chen, C. Zhao, Adv. Energy Mater. 2018, 8, 1801413.
- 31G. Zeng, B. Liu, U. Ali, Y. Li, H. Jia, M. Sun, Y. Li, Y. Hao, X. Yong, T. Wang, C. Wang, Appl. Catal. B 2024, 351.
- 32B. Han, D. Zhang, X. Liu, Z. Wang, W. Qu, S. Zhang, C. Deng, J. Mater. Chem. A 2022, 10, 13508.
- 33J. Ge, X. Yi, L. Fan, B. Lu, J. Energy Chem. 2021, 57, 28.
- 34K. Nakamoto, R. Sakamoto, Y. Sawada, M. Ito, S. Okada, Small Methods 2018, 3, 1800220
- 35X. y. Wu, M. y. Sun, Y. f. Shen, J. f. Qian, Y. l. Cao, X. p. Ai, H. x. Yang, ChemSusChem 2014, 7, 407.
- 36X. Wu, M. Sun, S. Guo, J. Qian, Y. Liu, Y. Cao, X. Ai, H. Yang, Chem. Nano Mater. 2015, 1, 188.
- 37H. Gao, J. B. Goodenough, Angew. Chem. 2016, 55, 12768.
- 38L. Suo, O. Borodin, Y. Wang, X. Rong, W. Sun, X. Fan, S. Xu, M. A. Schroeder, A. V. Cresce, F. Wang, C. Yang, Y. S. Hu, K. Xu, C. Wang, Adv. Energy Mater. 2017, 7, 1701189.
- 39Z. Hou, X. Li, J. Liang, Y. Zhu, Y. Qian, J. Mater. Chem. A 2015, 3, 1400.
- 40M. Pasta, C. D. Wessells, N. Liu, J. Nelson, M. T. McDowell, R. A. Huggins, M. F. Toney, Y. Cui, Nat. Commun. 2014, 5, 3007.
- 41A. J. Fernández-Ropero, D. Saurel, B. Acebedo, T. Rojo, M. Casas-Cabanas, J. Power Sources 2015, 291, 40.
- 42Y. Liu, L. Luo, Z. Shen, Y. Ji, Z. Wen, Z. Li, J. Li, P. Sun, J. Xie, G. Hong, Chem. Eng. J. 2023, 465, 142733.
- 43J. Song, L. Wang, Y. Lu, J. Liu, B. Guo, P. Xiao, J.-J. Lee, X.-Q. Yang, G. Henkelman, J. B. Goodenough, J. Am. Chem. Soc. 2015, 137, 2658.
- 44J. P. Perdew, J. A. Chevary, S. H. Vosko, K. A. Jackson, M. R. Pederson, D. J. Singh, C. Fiolhais, Phy. Rev. B 1992, 46, 6671.
- 45P. E. Blöchl, Phy. Rev. B 1994, 50, 17953.
- 46H. J. Monkhorst, J. D. Pack, Phy. Rev. B 1976, 13, 5188.
