SiOx Anode: From Fundamental Mechanism toward Industrial Application
Haoyu Li
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorHaodong Li
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorZhiwei Yang
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorLiwen Yang
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorJueying Gong
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorYuxia Liu
The Key Laboratory of Life-Organic Analysis, Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong, 273165 P. R. China
Search for more papers by this authorGongke Wang
School of Materials Science and Engineering, Henan Normal University, XinXiang, 453007 P. R. China
Search for more papers by this authorZhuo Zheng
College of Polymer Science and Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorBenhe Zhong
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorCorresponding Author
Yang Song
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
E-mail: [email protected], [email protected]
Search for more papers by this authorYanjun Zhong
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorZhenguo Wu
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorCorresponding Author
Xiaodong Guo
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
E-mail: [email protected], [email protected]
Search for more papers by this authorHaoyu Li
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorHaodong Li
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorZhiwei Yang
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorLiwen Yang
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorJueying Gong
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorYuxia Liu
The Key Laboratory of Life-Organic Analysis, Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong, 273165 P. R. China
Search for more papers by this authorGongke Wang
School of Materials Science and Engineering, Henan Normal University, XinXiang, 453007 P. R. China
Search for more papers by this authorZhuo Zheng
College of Polymer Science and Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorBenhe Zhong
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorCorresponding Author
Yang Song
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
E-mail: [email protected], [email protected]
Search for more papers by this authorYanjun Zhong
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorZhenguo Wu
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
Search for more papers by this authorCorresponding Author
Xiaodong Guo
School of Chemical Engineering, Sichuan University, Chengdu, 610065 P. R. China
E-mail: [email protected], [email protected]
Search for more papers by this authorAbstract
Silicon monoxide (SiO) has been explored and confirmed as a promising anode material of lithium-ion batteries. Compared with pure silicon, SiO possesses a more stable microstructure which makes better comprehensive electrochemical properties. However, the lithiation mechanism remains in dispute, and problems such as poor cyclability, unsatisfactory electrical conductivity, and low initial Coulombic efficiency (ICE) need to be addressed. Additionally, more attention needs to be paid on the internal relationship between electrochemical performances and structures. In this review, the different preparation processes, the derived microstructure of the SiOx, the corresponding lithiation mechanism, and electrochemical properties are summarized. Researches about disproportionation reaction which is regarded as a key point and other modifications are systematically introduced. Closely linked with structure, the advantages and disadvantages of various SiOx anode materials are summarized and analyzed, and the possible directions toward the practical applications of SiOx anode material are presented. In a word, from the preparation and reaction mechanism of the material to the modifications and future development, a complete and systematical review on SiOx anode is presented.
Conflict of Interest
The authors declare no conflict of interest.
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