Cubic and Hexagonal Mesostructured Hexarhenium Selenocyanides: Supramolecular Assemblies of Octahedral Nanoclusters†
Seong Huh
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Department of Chemistry and Protein Research Center for Bio-Industry Hankuk University of Foreign Studies, Yongin 449-791 (Korea)
Search for more papers by this authorMin-Jung Suh
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Search for more papers by this authorVo Vien
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Search for more papers by this authorYoungmee Kim
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Search for more papers by this authorCorresponding Author
Seong-Ju Hwang
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea).Search for more papers by this authorCorresponding Author
Sung-Jin Kim
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea).Search for more papers by this authorSeong Huh
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Department of Chemistry and Protein Research Center for Bio-Industry Hankuk University of Foreign Studies, Yongin 449-791 (Korea)
Search for more papers by this authorMin-Jung Suh
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Search for more papers by this authorVo Vien
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Search for more papers by this authorYoungmee Kim
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Search for more papers by this authorCorresponding Author
Seong-Ju Hwang
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea).Search for more papers by this authorCorresponding Author
Sung-Jin Kim
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea)
Department of Chemistry and Nano Sciences Ewha Womans University 11-1 Daehyun-Dong, Seodaemoon-Gu, Seoul 120-750 (Korea).Search for more papers by this authorThis research was funded by the SRC program of the Korea Science and Engineering Foundation (KOSEF) through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (grant R11-2005-008-00000-0) and by the Korea Research Foundation (grant KRF-2004-005-C00093).
Graphical Abstract
The octahedral [Re6Se8(CN)6]4− ions with various bridging metal ions form well-defined cubic and hexagonal mesostructures (see image) in the presence of liquid-crystal template in formamide. The interaction between the positively charged micellar head groups of the template and the [Re6Se8(CN)6]4− ions is a pure noncovalent electrostatic interaction. These materials are coordination polymers with exceptionally large 1D or 3D potential pores because of the dimension of mesoscale liquid-crystal template.
Supporting Information
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