High-Temperature Ferromagnetism of the Iron-Based FCC Phase: The Effect of Carbon and Nickel
Mikhail A. Uimin
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorAnatoly Ye. Yermakov
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Department of Magnetism and Magnetic Nanomaterials, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorAlexander V. Korolev
Laboratory of Ferromagnetic Alloys, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorMikhail I. Kurkin
Theoretical Physics Laboratory, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorAlexander S. Konev
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Laboratory of Radio Electronics and Electronics, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorSergey I. Novikov
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorCorresponding Author
Artem S. Minin
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Department of Biology and Fundamental Medicine, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorAlexey S. Volegov
Department of Magnetism and Magnetic Nanomaterials, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorVasily S. Gaviko
Laboratory of Ferromagnetic Alloys, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Department of Magnetism and Magnetic Nanomaterials, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorMikhail A. Uimin
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorAnatoly Ye. Yermakov
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Department of Magnetism and Magnetic Nanomaterials, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorAlexander V. Korolev
Laboratory of Ferromagnetic Alloys, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorMikhail I. Kurkin
Theoretical Physics Laboratory, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorAlexander S. Konev
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Laboratory of Radio Electronics and Electronics, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorSergey I. Novikov
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Search for more papers by this authorCorresponding Author
Artem S. Minin
Laboratory of Applied Magnetism, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Department of Biology and Fundamental Medicine, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorAlexey S. Volegov
Department of Magnetism and Magnetic Nanomaterials, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorVasily S. Gaviko
Laboratory of Ferromagnetic Alloys, M.N. Mikheev Institute of Metal Physics of UB of RAS, Yekaterinburg, 620108 Russia
Department of Magnetism and Magnetic Nanomaterials, Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, 620002 Russia
Search for more papers by this authorAbstract
The phase composition and magnetic properties of FeNi nanoparticles encapsulated in carbon with a nickel content of about 10% are studied in comparison with FeNi nanoparticles of similar composition without carbon coating. The Fe91Ni9 particles have the body centered cubic structure, whereas the Fe88Ni12@C particles have the face centered cubic (FCC) structure. The Fe88Ni12@C particles are characterized with a rather high magnetization of 60 emu g−1 in the field of 30 kOe at 5 K and 40 emu g−1 at 300 K. The monotonous behavior of magnetization with temperature gives grounds to assume that the Fe88Ni12@C particles retain the FCC structure over the entire temperature range down to 5 K. It is concluded that the stabilization of FCC phase of Fe88Ni12@C and the ferromagnetic state of this FCC phase are related to a large concentration of carbon in the core of the nanoparticles.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| pssb202200248-sup-0001-SuppData-S1.pdf674.4 KB | Supplementary Material |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1S. Klokov, E. Lokteva, E. Golubina, P. Chernavskii, K. Maslakov, T. Egorova, S. Chernyak, A. Minin, A. Konev, Appl. Surf. Sci. 2019, 463, 395.
- 2N. Cai, H. Yang, X. Zhang, S. Xia, D. Yao, P. Bartocci, F. Fantozzi, Y. Chen, H. Chen, P. T. Williams, Waste Manage. 2020, 109, 119.
- 3S. T. Neeli, H. Ramsurn, Carbon 2018, 134, 480.
- 4V. Galakhov, A. S. Shkvarin, A. Semenova, M. Uimin, A. Mysik, N. Shchegoleva, A. Y. Yermakov, E. Kurmaev, J. Phys. Chem. C 2010, 114, 22413.
- 5E. Shafranovsky, Y. I. Petrov, L. Casas, E. Molins, J. Nanopart. Res. 2011, 13, 4913.
- 6A. Y. Yermakov, M. Uimin, I. Byzov, A. Konev, S. Novikov, A. Minin, V. Gaviko, A. Murzakaev, V. Maikov, Mater. Lett. 2019, 254, 202.
- 7A. D. Romig, J. Goldstein, Metall. Trans. A 1980, 11, 1151.
- 8R. N. Bhowmik, P. D. Babu, A. K. Sinha, A. Bhisikar, Inorg. Chem. 2020, 59, 6763.
- 9M. Uimin, S. Novikov, A. Konev, I. Byzov, A. Y. Yermakov, A. Minin, D. Privalova, V. Gaviko, N. Shchegoleva, Phys. Met. Metallogr. 2019, 120, 228.
- 10P. V. Hendriksen, S. Linderoth, P.-A. Lindgård, Phys. Rev. B 1993, 48, 7259.
- 11S. Komogortsev, R. Iskhakov, A. Balaev, A. Kudashov, A. Okotrub, S. Smirnov, Phys. Solid State 2007, 49, 734.
- 12N. T. Lan, N. P. Duong, T. D. Hien, J. Alloys Compd. 2011, 509, 5919.
- 13J. Xavier, R. da Silva, J. Araújo, C. Iglesias, E. Silva Filho, J. Fonseca, J. Soares, P. Souza, C. P. Cid, M. Gamino, S. N. de Medeiros, M. A. Correa, F. Bohn, J. Alloys Compd. 2021, 889, 161650.
- 14R. Bhowmik, K. Aneeshkumar, J. Magn. Magn. Mater. 2018, 460, 177.
- 15C. Vázquez-Vázquez, M. López-Quintela, M. Buján-Núñez, J. Rivas, J. Nanopart. Res. 2011, 13, 1663.
- 16B. Aslibeiki, G. Varvaro, D. Peddis, P. Kameli, J. Magn. Magn. Mater. 2017, 422, 7.
- 17W. Kümmerle, U. Gradmann, Solid State Commun. 1977, 24, 33.
- 18U. Gradmann, H. Isbert, J. Magn. Magn. Mater. 1980, 15, 1109.
- 19B. Wei, M. Shima, R. Pati, S. K. Nayak, D. J. Singh, R. Ma, Y. Li, Y. Bando, S. Nasu, P. M. Ajayan, Small 2006, 2, 804.
- 20X. Dong, Z. Zhang, S. Jin, W. Sun, X. Zhao, Z. Li, Y. Chuang, J. Mater. Res. 1999, 14, 1782.
- 21V. Tsurin, A. Y. Yermakov, M. Uimin, A. Mysik, N. Shchegoleva, V. Gaviko, V. Maikov, Phys. Solid State 2014, 56, 287.
- 22S. Ishio, K. Nushiro, M. Takahashi, J. Phys. F: Met. Phys. 1986, 16, 1093.
- 23R. Weiss, Proc. Phys. Soc. (1958-1967) 1963, 82, 281.
- 24P. Gorria, D. Martínez-Blanco, J. A. Blanco, A. Hernando, J. S. Garitaonandia, L. F. Barqun, J. Campo, R. I. Smith, Phys. Rev. B 2004, 69, 214421.
- 25M. Shiga, Y. Nakamura, J. Magn. Magn. Mater. 1984, 40, 319.
- 26A. Safronov, G. Kurlyandskaya, A. Chlenova, M. Kuznetsov, D. Bazhin, I. Beketov, M. Sanchez-Ilarduya, A. Martinez-Amesti, Langmuir 2014, 30, 3243.
- 27X. Liu, Z. Ou, D. Geng, Z. Han, J. Jiang, W. Liu, Z. Zhang, Carbon 2010, 48, 891.
