Volume 33, Issue 6 2400035
Research Article

An Algorithm for Computing Entanglements in an Ensemble of Linear Polymers

Pramod Kumar Patel

Pramod Kumar Patel

Department of Mechanical Engineering, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh, 208016 INDIA

Search for more papers by this author
Sumit Basu

Corresponding Author

Sumit Basu

Department of Mechanical Engineering, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh, 208016 INDIA

E-mail: [email protected]

Search for more papers by this author
First published: 22 July 2024
Citations: 1

Abstract

The entanglement length plays a key role in deciding many important properties of thermoplastics. A number of computational techniques exist for the determination of entanglement length. In Ahmad et al.,[1] a method is proposed that treats a macromolecular chain as a 1D open curve and identifies entanglements by computing the linking number between two such interacting curves. If the curves wind around each other, a topological entanglement is detected. However, the entanglement length that is measured in experiments is assumed to be between rheological entanglements, which are clusters of such topological entanglements that collectively anchor the interacting chains strongly. In this article, the method of clustering topological entanglements into rheological ones is further elaborated and the robustness of the method is assessed. It is shown that this method estimates an entanglement length that depends on the forcefield chosen and is reasonably constant for chain lengths longer than the entanglement length. For shorter chain lengths, the method returns an infinite value of entanglement length indicating that the sample is unentangled. Moreover, in spite of using a geometry-based algorithm for clustering topological entanglements, the estimated entanglement length retains known empirical connections with physical attributes associated with the ensemble.

Conflict of Interest

The authors declare no conflict of interest.

Data Availability Statement

The data that support the findings of this study are available in the supplementary material of this article.

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.