Synthesis of Hydroxy-Functionalized Cyclic Olefin Copolymer and Its Block Copolymers with Semicrystalline Polyolefin Segments
Xiangyang Song
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Donghua University, Shanghai, 201620 China
Search for more papers by this authorLijun Yu
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Donghua University, Shanghai, 201620 China
Search for more papers by this authorCorresponding Author
Takeshi Shiono
Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527 Japan
E-mail: [email protected], [email protected]Search for more papers by this authorTariqul Hasan
Department of Chemistry, Rajshahi University, Rajshahi, 6205 Bangladesh
Search for more papers by this authorCorresponding Author
Zhengguo Cai
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Donghua University, Shanghai, 201620 China
E-mail: [email protected], [email protected]Search for more papers by this authorXiangyang Song
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Donghua University, Shanghai, 201620 China
Search for more papers by this authorLijun Yu
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Donghua University, Shanghai, 201620 China
Search for more papers by this authorCorresponding Author
Takeshi Shiono
Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527 Japan
E-mail: [email protected], [email protected]Search for more papers by this authorTariqul Hasan
Department of Chemistry, Rajshahi University, Rajshahi, 6205 Bangladesh
Search for more papers by this authorCorresponding Author
Zhengguo Cai
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Material Science and Engineering, Donghua University, Shanghai, 201620 China
E-mail: [email protected], [email protected]Search for more papers by this authorAbstract
Synthesis of hydroxy-functionalized cyclic olefin copolymer (COC) is achieved with remarkably high activity (up to 5.96 × 107 g-polymer mol-Ti−1 h−1) and controlled hydroxy group in a wide range (≈17.1 mol%) by using ansa-dimethylsilylene (fluorenyl)(amido)titanium complex. The catalyst also promotes living/controlled copolymerization to afford novel diblock copolymers consisting of hydroxy-functionalized COC and semicrystalline polyolefin sequence such as polyethylene and syndiotactic polypropylene, where the glass transition temperature of the norbornene/10-undecen-1-ol segment and each block length are controlled by comonomer composition and copolymerization time, respectively.
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