Synergy of B and Al Dopants in Mesoporous MFI Nanocrystals for Highly Selective Alcoholysis of Furfuryl Alcohol into Ethyl Levulinate
Meng-Ying Wang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorHui Su
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorGuang-Yao Zhai
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorQiu-Ying Yu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorHong-Hui Wang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorCorresponding Author
Zhi-Dong Jiang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorCorresponding Author
Xin-Hao Li
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorJie-Sheng Chen
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorMeng-Ying Wang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorHui Su
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorGuang-Yao Zhai
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorQiu-Ying Yu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorHong-Hui Wang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorCorresponding Author
Zhi-Dong Jiang
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorCorresponding Author
Xin-Hao Li
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorJie-Sheng Chen
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. C
Search for more papers by this authorAbstract
In this article, the synergetic effect between the B- and Al-based acidic sites in B–Al co-doped mesoporous MFI nanocrystals (denoted as m-B-Al-S1) is rationally applied to modify the alcoholysis process of furfuryl alcohol. The porosity and dopant concentration of the m-B-Al-S1 materials are optimized via a modified Kirkendall growth method to boost the ultra-high selectivity to ethyl levulinate reactions (94%). The m-B-Al-S1 catalyst also shows good stability for further reuses.
Conflict of Interest
The authors declare no conflicts of interest.
Supporting Information
| Filename | Description |
|---|---|
| ente201900271-sup-0001-SuppData-S1.doc1.8 MB | Supplementary |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1J. A. Melero, J. Iglesias, A. Garcia, Energy Environ. Sci. 2012, 5, 7393.
- 2C. H. Zhou, X. Xia, C. X. Lin, D. S. Tong, J. Beltramini, Chem. Soc. Rev. 2011, 40, 5588.
- 3M. Wang, J. Ma, H. Liu, N. Luo, Z. Zhao, F. Wang, ACS Catal. 2018, 8, 2129.
- 4Y. B. Huang, T. Yang, M. C. Zhou, H. Pan, Y. Fu, Green Chem. 2016, 18, 1516.
- 5S. Saravanamurugan, A. Riisager, Catal. Commun. 2012, 17, 71.
- 6S. S. Enumula, K. S. Koppadi, V. R. Gurram, D. R. Burri, S. R. Kamaraju, Sustainable Energy Fuels 2017, 1, 644.
- 7E. Ahmad, M. I. Alam, K. K. Pant, M. A. Haider, Green Chem. 2016, 18, 4804.
- 8M. S. Tiwari, A. B. Gawade, G. D. Yadav, Green Chem. 2017, 19, 963.
- 9J. P. Lange, W. D. van de Graaf, R. J. Haan, ChemSusChem 2009, 2, 437.
- 10K. Y. Nandiwale, A. M. Pande, V. V. Bokade, RSC Adv. 2015, 5, 79224.
- 11D. Zhao, P. Prinsen, Y. Wang, W. Ouyang, F. Delbecq, C. Len, R. Luque, ACS Sustainable Chem. Eng. 2018, 6, 6901.
- 12A. Chappaz, J. Lai, K. De Oliveira Vigier, D. Morvan, R. Wischert, M. Corbet, B. Doumert, X. Trivelli, A. Liebens, F. Jérôme, ACS Sustainable Chem. Eng. 2018, 6, 4405.
- 13F. J. Liu, K. Huang, A. Zheng, F. S. Xiao, S. Dai, ACS Catal. 2018, 8, 372.
- 14P. Neves, S. Lima, M. Pillinger, S. M. Rocha, J. Rocha, A. A. Valente, Catal. Today 2013, 218, 76.
- 15R. Bai, Q. Sun, N. Wang, Y. C. Zou, G. Q. Guo, S. Iborra, A. Corma, J. H. Yu, Chem. Mater. 2016, 28, 6455.
- 16B. Lu, S. An, D. Y. Song, F. Su, X. Yang, Y. H. Guo, Green Chem. 2015, 17, 1767.
- 17S. H. Zhu, C. M. Chen, Y. F. Xue, J. B. Wu, J. G. Wang, W. B. Fan, ChemCatChem 2014, 6, 3080.
- 18G. F. Wang, Z. Q. Zhang, L. H. Song, Green Chem. 2014, 16, 1436.
- 19T. L. Cui, X. H. Li, L. B. Lv, K. X. Wang, J. Su, J. S. Chen, Chem. Commun. 2015, 51, 12563.
- 20Y. S. Yang, C. Sun, J. M. Du, Y. H. Yue, W. M. Hua, C. L. Zhang, W. Shen, H. L. Xu, Catal. Commun. 2012, 24, 44.
- 21W. P. Zhang, D. Ma, X. W. Han, X. M. Liu, X. H. Bao, X. W. Guo, X. S. Wang, J. Catal. 1999, 188, 393.
- 22B. Bonelli, L. Forni, A. Aloise, J. B. Nagy, G. Fornasari, E. Garrone, A. Gedeon, G. Giordano, F. Trifirò, Microporous Mesoporous Mater. 2007, 101, 153.
- 23S. Fathi, M. Sohrabi, C. Falamaki, Fuel 2014, 116, 529.
- 24T. L. Cui, L. B. Lv, W. B. Zhang, X. H. Li, J. S. Chen, Catal. Sci. Technol. 2016, 6, 5262.
- 25X. J. Kong, X. L. Zhang, C. Han, C. C. Li, L. H. Yu, J. H. Liu, Mol. Catal. 2017, 443, 186.
- 26T. L. Cui, W. Y. Ke, W. B. Zhang, H. H. Wang, X. H. Li, J. S. Chen, Angew. Chem., Int. Ed. 2016, 55, 9178.
- 27W. Y. Ke, T. L. Cui, Q. Y. Yu, M. Y. Wang, L. B. Lv, H. H. Wang, Z. D. Jiang, X. H. Li, J. S. Chen, Nano Res. 2018, 11, 874
Citing Literature
