Potassium-Based α-Manganese Dioxide Nanofiber Binder-Free Self-Supporting Electrodes: A Design Strategy for High Energy Density Batteries
Dr. Altug S. Poyraz
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorJianping Huang
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorDr. Lijun Wu
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorDr. David C. Bock
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorProf. Yimei Zhu
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorCorresponding Author
Prof. Amy C. Marschilok
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Department of Materials Science and Engineering, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorCorresponding Author
Prof. Kenneth J. Takeuchi
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Department of Materials Science and Engineering, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorCorresponding Author
Prof. Esther S. Takeuchi
Brookhaven National Laboratory, Upton, NY, 11973 USA
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Department of Materials Science and Engineering, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorDr. Altug S. Poyraz
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorJianping Huang
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorDr. Lijun Wu
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorDr. David C. Bock
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorProf. Yimei Zhu
Brookhaven National Laboratory, Upton, NY, 11973 USA
Search for more papers by this authorCorresponding Author
Prof. Amy C. Marschilok
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Department of Materials Science and Engineering, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorCorresponding Author
Prof. Kenneth J. Takeuchi
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Department of Materials Science and Engineering, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorCorresponding Author
Prof. Esther S. Takeuchi
Brookhaven National Laboratory, Upton, NY, 11973 USA
Department of Chemistry, Stony Brook University, Stony Brook, NY, 11794 USA
Department of Materials Science and Engineering, Stony Brook University, Stony Brook, NY, 11794 USA
Search for more papers by this authorAbstract
This work minimizes the passive components of electrodes and moves toward bridging the gap between actual and theoretical battery gravimetric energy density. Binder-free self-supporting (BFSS) cathodes were prepared from redox-active, high aspect ratio, potassium α-MnO2 nanofibers (K-OMS-2) by eliminating the binder and current collector. The electroactive and structural element, K-OMS-2, was prepared by using a scalable, moderate temperature, aqueous synthesis. The BFFS electrode approach allows fabrication of thick, high energy density electrodes with low impedance, with up to 10-fold improvement in delivered specific energy relative to conventional cathodes. This could enable the design of high-capacity large form factor cells, as required for applications demanding high energy content. In principle, this approach suggests a widely applicable paradigm for the construction of other BFFS electrodes through the targeted synthesis of other transition-metal oxides with high aspect, fibrous morphologies.
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