Dynamically Securing the Data by 1O2 Sensitization of Fluorescent Composites with a High Latency and Uncrackable Features
Yuanyuan Chen
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
These authors contributed equally to this work.
Search for more papers by this authorJiamao Chen
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
These authors contributed equally to this work.
Search for more papers by this authorHuacan Wu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049 China
Search for more papers by this authorYifan Liu
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
Search for more papers by this authorCorresponding Author
Donghui Wang
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049 China
E-mail: [email protected]Search for more papers by this authorWeiguo Huang
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049 China
Search for more papers by this authorYuanyuan Chen
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
These authors contributed equally to this work.
Search for more papers by this authorJiamao Chen
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
These authors contributed equally to this work.
Search for more papers by this authorHuacan Wu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049 China
Search for more papers by this authorYifan Liu
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
Search for more papers by this authorCorresponding Author
Donghui Wang
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049 China
E-mail: [email protected]Search for more papers by this authorWeiguo Huang
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian, 350002 China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002 China
University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049 China
Search for more papers by this authorComprehensive Summary
Dynamic fluorescent materials play a crucial role in secure inks for data encryption; however, they are still plagued by issues such as photodegradation, poor latency, and susceptibility to unauthorized access. Herein, we propose a photochemically modulated dynamic fluorescent encryption system based on 1O2 sensitization of fluorescent composites, comprising a 1O2-sensitive fluorophore (F2) and non-emissive polymers. After UV irradiation, in-situ generated 1O2 from the polymer effectively binds with F2 to form endoperoxides (F2EPO), resulting in a significant redshift in emission, up to 150 nm. The 1O2 concentration is closely related to the irradiation time, rendering different fluorescent colors in a time-gated fashion. Moreover, the emission of F2EPO can be regulated by polymer chemical structure, molecular weight, and crosslinking density. Relying on these merits, we develop a dynamic data encryption method with various non-emissive polymers as the data storage media, UV light irradiation as the data encoder, and F2 as the data decoder. UV light irradiation of diverse polymer solutions generates 1O2 at different concentrations, effectively encoding the data, which remains invisible under both UV and natural lights. The addition of F2 to these irradiated polymer solutions produces different redshifted fluorescence, enabling secure data decryption. Attributing to the non-emissive nature of the polymers, time-gated readout fashion, excellent latency of 1O2, and subtle interactions between 1O2 and F2, this data encryption is nearly undecipherable. This work offers an advantage data encryption approach beyond the reach of conventional fluorophores.
Supporting Information
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| cjoc202300773-sup-0001-Supinfo.pdfPDF document, 1.9 MB |
Appendix S1: Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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