Volume 43, Issue 18
Isocyclic Compounds

ChemInform Abstract: Efficient Fe/I2/NaI-Mediated Synthesis of Alkenyl Iodides Through Direct Coupling of Alcohols and Alkynes.

Ming-Ming Li

Ming-Ming Li

Chengdu Inst. Biol., Chin. Acad. Sci., Chengdu 610041, Peop. Rep. China

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Qiang Zhang

Qiang Zhang

Chengdu Inst. Biol., Chin. Acad. Sci., Chengdu 610041, Peop. Rep. China

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Hui-Lan Yue

Hui-Lan Yue

Chengdu Inst. Biol., Chin. Acad. Sci., Chengdu 610041, Peop. Rep. China

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Lei Ma

Lei Ma

Chengdu Inst. Biol., Chin. Acad. Sci., Chengdu 610041, Peop. Rep. China

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Jian-Xin Ji

Jian-Xin Ji

Chengdu Inst. Biol., Chin. Acad. Sci., Chengdu 610041, Peop. Rep. China

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First published: 05 April 2012

Abstract

Reaction of secondary alcohols with alkynes under optimized conditions A) produces E/Z-isomeric mixtures of the synthetically important structural motifs with the (E) isomer always predominating.

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