ChemInform Abstract: Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes.
Abstract
The utility of ortho,ortho′-disubstituted triazolium derivatives as NHC-catalysts in the preparation of enantioenriched acyl cyclopropanes is demonstrated.