Volume 43, Issue 18
Isocyclic Compounds

ChemInform Abstract: Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes.

Fan Liu

Fan Liu

Org.-Chem. Inst., Westfael. Wilhelms Univ., D-48149 Muenster, Germany

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Xavier Bugaut

Xavier Bugaut

Org.-Chem. Inst., Westfael. Wilhelms Univ., D-48149 Muenster, Germany

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Michael Schedler

Michael Schedler

Org.-Chem. Inst., Westfael. Wilhelms Univ., D-48149 Muenster, Germany

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Roland Froehlich

Roland Froehlich

Org.-Chem. Inst., Westfael. Wilhelms Univ., D-48149 Muenster, Germany

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Frank Glorius

Frank Glorius

Org.-Chem. Inst., Westfael. Wilhelms Univ., D-48149 Muenster, Germany

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First published: 05 April 2012

Abstract

The utility of ortho,ortho′-disubstituted triazolium derivatives as NHC-catalysts in the preparation of enantioenriched acyl cyclopropanes is demonstrated.

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