Volume 43, Issue 18
Preparative Organic Chemistry

ChemInform Abstract: Enantioselective Intermolecular Carbon—Carbon Bond Formation of Glyoxylate Imines with Allylstannanes Catalyzed by tropos BIPHEP—Gold(I) Complexes with Au—Au Interactions.

Masafumi Kojima

Masafumi Kojima

Dep. Appl. Chem., Tokyo Inst. Technol., Meguro, Tokyo 152, Japan

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Koichi Mikami

Koichi Mikami

Dep. Appl. Chem., Tokyo Inst. Technol., Meguro, Tokyo 152, Japan

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First published: 05 April 2012

Abstract

The present study reveals the advantage of tropos BIPHEP—gold(I) complexes with intramolecular Au—Au interactions compared to the structurally similar atropos BINAP—gold complexes without the Au—Au interaction.

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