ChemInform Abstract: Enantioselective Intermolecular Carbon—Carbon Bond Formation of Glyoxylate Imines with Allylstannanes Catalyzed by tropos BIPHEP—Gold(I) Complexes with Au—Au Interactions.
Abstract
The present study reveals the advantage of tropos BIPHEP—gold(I) complexes with intramolecular Au—Au interactions compared to the structurally similar atropos BINAP—gold complexes without the Au—Au interaction.