Volume 43, Issue 18
Preparative Organic Chemistry

ChemInform Abstract: Titanium(IV) Enolates of 2-Nitrocarboxylic Esters and Their Oxidative Chlorination. A Convenient Route to α-Chloro-α-nitrocarboxylates.

Dariusz Ciez

Dariusz Ciez

Fac. Chem., Jagiellonian Univ., PL-30-060 Krakow, Pol.

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Justyna Kalinowska-Tluscik

Justyna Kalinowska-Tluscik

Fac. Chem., Jagiellonian Univ., PL-30-060 Krakow, Pol.

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First published: 05 April 2012

Abstract

The novel method involves oxidative chlorination of titanium(IV) enolates derived from esters (I) and (III) in the presence ammonium nitrate.

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