Volume 42, Issue 21
Organoelement Compounds

ChemInform Abstract: A General Synthetic Method for 1,1′-Bis(diacetylene-group)-Connected Ferrocene and π-Electronic System.

Junro Yoshino

Junro Yoshino

Grad. Sch. Sci. Eng., Univ. Toyama, Gofuku, Toyama 930, Japan

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Rumi Shimizu

Rumi Shimizu

Grad. Sch. Sci. Eng., Univ. Toyama, Gofuku, Toyama 930, Japan

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Naoto Hayashi

Naoto Hayashi

Grad. Sch. Sci. Eng., Univ. Toyama, Gofuku, Toyama 930, Japan

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Hiroyuki Higuchi

Hiroyuki Higuchi

Grad. Sch. Sci. Eng., Univ. Toyama, Gofuku, Toyama 930, Japan

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First published: 28 April 2011

Abstract

Under modified Eglinton oxidative coupling conditions, it is possible to generate 1,1′-diethynylferrocene in situ from a trimethylsilyl-protected precursor (I) and to react it with other terminal alkenes (III).

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