Volume 42, Issue 21
Physical Inorganic Chemistry

ChemInform Abstract: Preparation and Superconductivity of New Stage and Polytypic Phases in Potassium-Intercalated Zirconium Nitride Chloride (KxZrNCl).

Zhanfeng Zheng

Zhanfeng Zheng

Dep. Appl. Chem., Fac. Eng., Hiroshima Univ., Higashi-Hiroshima 739, Japan

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Shoji Yamanaka

Shoji Yamanaka

Dep. Appl. Chem., Fac. Eng., Hiroshima Univ., Higashi-Hiroshima 739, Japan

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First published: 28 April 2011

Abstract

New polytypic and intermediate-stage intercalation compounds K0.26ZrNCl, K0.08(thf)yZrNCl, and K0.26(pc)yZrNCl (pc: propylene carbonate) with different amounts of potassium and cointercalation of THF are prepared from a K-naphthalene solution in THF, and a direct reaction with potassium metal.

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