ChemInform Abstract: Preparation and Superconductivity of New Stage and Polytypic Phases in Potassium-Intercalated Zirconium Nitride Chloride (KxZrNCl).
Abstract
New polytypic and intermediate-stage intercalation compounds K0.26ZrNCl, K0.08(thf)yZrNCl, and K0.26(pc)yZrNCl (pc: propylene carbonate) with different amounts of potassium and cointercalation of THF are prepared from a K-naphthalene solution in THF, and a direct reaction with potassium metal.