Ammonium-Based Polymer Ionic Liquid Membrane for Wastewater Treatment and Bioenergy Production
Hasna Addi
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Université Mohammed V, Laboratoire de Mécanique, Procédés et Processus Industriels (LM2PI), Sciences Chimiques Ecole Normale Supérieure de l'Enseignement Technique (ENSET), 30100 Souiss Rabat, Morocco
Search for more papers by this authorFrancisco Mateo-Ramírez
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Search for more papers by this authorMaria J. Salar-García
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain
Search for more papers by this authorVictor M. Ortiz-Martínez
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain
Search for more papers by this authorCorresponding Author
Francisco J. Hernández-Fernández
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Correspondence: Francisco J. Hernández-Fernández ([email protected]), Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain. University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain.Search for more papers by this authorCorresponding Author
Antonia P. de los Ríos
University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain
Correspondence: Francisco J. Hernández-Fernández ([email protected]), Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain. University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain.Search for more papers by this authorCarlos Godínez
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Search for more papers by this authorEl Mustapha Lotfi
Université Mohammed V, Laboratoire de Mécanique, Procédés et Processus Industriels (LM2PI), Sciences Chimiques Ecole Normale Supérieure de l'Enseignement Technique (ENSET), 30100 Souiss Rabat, Morocco
Search for more papers by this authorMohamed El Mahi
Université Mohammed V, Laboratoire de Mécanique, Procédés et Processus Industriels (LM2PI), Sciences Chimiques Ecole Normale Supérieure de l'Enseignement Technique (ENSET), 30100 Souiss Rabat, Morocco
Search for more papers by this authorLuis J. Lozano-Blanco
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Search for more papers by this authorHasna Addi
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Université Mohammed V, Laboratoire de Mécanique, Procédés et Processus Industriels (LM2PI), Sciences Chimiques Ecole Normale Supérieure de l'Enseignement Technique (ENSET), 30100 Souiss Rabat, Morocco
Search for more papers by this authorFrancisco Mateo-Ramírez
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Search for more papers by this authorMaria J. Salar-García
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain
Search for more papers by this authorVictor M. Ortiz-Martínez
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain
Search for more papers by this authorCorresponding Author
Francisco J. Hernández-Fernández
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Correspondence: Francisco J. Hernández-Fernández ([email protected]), Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain. University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain.Search for more papers by this authorCorresponding Author
Antonia P. de los Ríos
University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain
Correspondence: Francisco J. Hernández-Fernández ([email protected]), Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain. University of Murcia, Department of Chemical Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus de Espinardo, 30100 Murcia, Spain.Search for more papers by this authorCarlos Godínez
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Search for more papers by this authorEl Mustapha Lotfi
Université Mohammed V, Laboratoire de Mécanique, Procédés et Processus Industriels (LM2PI), Sciences Chimiques Ecole Normale Supérieure de l'Enseignement Technique (ENSET), 30100 Souiss Rabat, Morocco
Search for more papers by this authorMohamed El Mahi
Université Mohammed V, Laboratoire de Mécanique, Procédés et Processus Industriels (LM2PI), Sciences Chimiques Ecole Normale Supérieure de l'Enseignement Technique (ENSET), 30100 Souiss Rabat, Morocco
Search for more papers by this authorLuis J. Lozano-Blanco
Technical University of Cartagena, Department of Chemical and Environmental Engineering, Regional Campus of International Excellence “Campus Mare Nostrum”, Campus La Muralla, 30202 Cartagena, Murcia, Spain
Search for more papers by this authorAbstract
Air-breathing cathode microbial fuel cells (MFCs) fed with citrus juice processing wastewater were employed for bioenergy production and simultaneously for wastewater treatment. Polymer inclusion membranes based on the ionic liquid methyltrioctylammonium chloride were tested as separator in this microbial fuel cell assembly. Regarding the wastewater treatment capacity, the evolution of the chemical oxygen demand (COD) removal over time reaches a maximum value of 45 %. In addition to COD removal, an electrochemical characterization of the wastewater before and after being treated was also performed. Despite this type of feedstock not being ideal for bioenergy production in air-breathing cathode MFCs due to the acidity of the substrate, enough amount of bioenergy is produced to consider this technology a suitable alternative for reusing citrus juice processing wastewater.
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