Excess dopant effect in platinum-based alloys toward the oxygen electroreduction reaction
Mrinal Kanti Kabiraz
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorHee Jin Kim
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorYoungmin Hong
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorQiaowan Chang
Department of Chemical Engineering, Columbia University, New York, New York, USA
Search for more papers by this authorCorresponding Author
Sang-Il Choi
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Department of Hydrogen and Renewable Energy, Kyungpook National University, Daegu, South Korea
CE Square Corp., Daegu, South Korea
Correspondence
Sang-Il Choi, Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Search for more papers by this authorMrinal Kanti Kabiraz
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorHee Jin Kim
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorYoungmin Hong
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorQiaowan Chang
Department of Chemical Engineering, Columbia University, New York, New York, USA
Search for more papers by this authorCorresponding Author
Sang-Il Choi
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, South Korea
Department of Hydrogen and Renewable Energy, Kyungpook National University, Daegu, South Korea
CE Square Corp., Daegu, South Korea
Correspondence
Sang-Il Choi, Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Search for more papers by this authorMrinal Kanti Kabiraz and Hee Jin Kim contributed equally to this study.
Funding information: National Research Foundation of Korea, Grant/Award Numbers: 2020R1I1A1A01072100, 2021R1A2C4001411, 2022R1I1A1A01064467
Abstract
Doping the PtNi octahedra with trace amount of transition metals has recently been shown to significantly improve the activity and durability of the oxygen reduction reaction (ORR). However, the role of excessive amounts of doped elements on ORR performance is unclear. In this work, PtNi octahedra were synthesized with and without excess Mo dopant. Also, spherical PtNi nanoparticles containing excess Co dopant were synthesized. The ORR performance revealed that PtNiMo octahedra and PtNiCo nanoparticles showed inferior ORR activities compared to bimetallic PtNi octahedra. Based on the electrochemical analysis, we found that unfavorable oxygen-binding strengths of PtNiMo and PtNiCo catalysts decrease the ORR performances.
Supporting Information
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| bkcs12588-sup-0001-Supinf.docxWord 2007 document , 1.8 MB | Appendix S1 Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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