Uncoordinated tetrazole ligands in metal–organic frameworks for proton-conductivity studies
Daeyeon Lee
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorSangho Lee
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorYounghu Son
Department of Chemistry, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorJun Yeong Kim
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorSeungheon Cha
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorDongmin Kwak
Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon, South Korea
Search for more papers by this authorCorresponding Author
Jooyeon Lee
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Jaesung Kwak
Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Minyoung Yoon
Department of Chemistry, Kyungpook National University, Daegu, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Min Kim
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorDaeyeon Lee
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorSangho Lee
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorYounghu Son
Department of Chemistry, Kyungpook National University, Daegu, South Korea
Search for more papers by this authorJun Yeong Kim
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorSeungheon Cha
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Search for more papers by this authorDongmin Kwak
Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon, South Korea
Search for more papers by this authorCorresponding Author
Jooyeon Lee
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Jaesung Kwak
Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Minyoung Yoon
Department of Chemistry, Kyungpook National University, Daegu, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorCorresponding Author
Min Kim
Department of Chemistry, Chungbuk National University, Cheongju, South Korea
Correspondence
Jooyeon Lee, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Jaesung Kwak, Infectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Research, Daejeon 34114, South Korea.
Email: [email protected]
Minyoung Yoon, Department of Chemistry, Kyungpook National University, Daegu 41566, South Korea.
Email: [email protected]
Min Kim, Department of Chemistry, Chungbuk National University, Cheongju 28644, South Korea.
Email: [email protected]
Search for more papers by this authorDaeyeon Lee, Sangho Lee, and Younghu Son contributed equally to this work.
Dedication on the occasion of Professor Sukbok Chang's 60th birthday.
Funding information: 2021 Undergraduate Research Program (URP); National Research Foundation of Korea (NRF) Global Ph.D. Fellowship Program, Grant/Award Number: 2019H1A2A1076014
Abstract
Zr-based metal–organic frameworks (MOFs) were modified with pendant tetrazole ligands for proton conductivity studies. Although tetrazolate ligands coordinated to metal cations have been widely utilized to construct MOFs or porous coordination polymers, to date, the use of uncoordinated tetrazole groups in MOFs has been limited. In this study, a benzene-1,4-dicarboxylic acid with pendant tetrazole groups (BDC-N4) was synthesized and used to prepare a Zr-based UiO-66 MOF using a mixed-ligand strategy. The tetrazole-functionalized UiO-66-N4 was compared to MOFs containing other acidic functional groups (hydroxyl, carboxylic acid, and sulfonic acid) with respect to their proton conductivities and acidities (calculated pKa). Interestingly, UiO-66-N4 showed a significant decrease in the activation energy with increase in the amount of added tetrazole groups, suggesting the Grotthuss proton conduction mechanism for uncoordinated tetrazole-containing MOFs.
CONFLICT OF INTEREST
The authors declare no conflict of interest.
Supporting Information
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| bkcs12539-sup-0001-Supinfo.docxWord 2007 document , 4 MB | Appendix S1 Supporting Information. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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