Volume 142, Issue 2 e56330

RESEARCH ARTICLE

The effect of rubber and plastic mass ratio on the compatibilized ethylene propylene diene monomer/polypropylene TPV with shape memory behavior

Mengmeng Xu,

Mengmeng Xu

orcid.org/0009-0002-3901-9342

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China

Contribution: Conceptualization (lead), Investigation (lead), Writing - original draft (lead)

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Liheng Chen,

Liheng Chen

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China

Contribution: Investigation (supporting)

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Chengzhong Zong,

Corresponding Author

Chengzhong Zong

[email protected]

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China

Correspondence

Chengzhong Zong, School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266011, China.

Email: [email protected]

Contribution: Resources (lead), Supervision (lead), Writing - review & editing (supporting)

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Mengmeng Xu,

Mengmeng Xu

orcid.org/0009-0002-3901-9342

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China

Contribution: Conceptualization (lead), Investigation (lead), Writing - original draft (lead)

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Liheng Chen,

Liheng Chen

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China

Contribution: Investigation (supporting)

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Chengzhong Zong,

Corresponding Author

Chengzhong Zong

[email protected]

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China

Correspondence

Chengzhong Zong, School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266011, China.

Email: [email protected]

Contribution: Resources (lead), Supervision (lead), Writing - review & editing (supporting)

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First published: 19 October 2024

https://doi.org/10.1002/app.56330

Citations: 2

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Abstract

Thermoplastic vulcanizate (TPV) with shape memory performance showed great application potential in various fields. In this work, the effect of the mass ratio of ethylene propylene diene monomer (EPDM) and polypropylene (PP) on the performance of TPV with sea island microstructure compatibilized by magnesium maleate (MgMA) and maleic anhydride (MAH) was studied. The compatibilized TPV 70/30 and TPV 60/40 obtained good shape memory property with the shape fixity ratio (R_f) and shape recovery ratio (R_r) of 87.3%, 96.7% and 91%, 86.6% respectively. R_f increased with more PP content and decreased with more EPDM content, however R_r decreased with more PP content and increased with more EPDM content. The maximum R_f of 95.4% and the maximum R_r of 100% of TPV were obtained at the EPDM/PP mass ratio of 20/80 and 80/20 respectively. The tensile strength and elongation at break of TPV increased with more PP content in the blend. The result of DMA, Fourier transform infrared (FTIR), and SEM demonstrated the compatibility effect of MgMA and MAH on EPDM and PP interface.

CONFLICT OF INTEREST STATEMENT

The authors declare no conflicts of interest.

Open Research

DATA AVAILABILITY STATEMENT

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Supporting Information

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Volume142, Issue2

January 10, 2025

e56330

Filename	Description
app56330-sup-0001-supinfo.docxWord 2007 document , 1.4 MB	Data S1. Supporting Information.
app56330-sup-0002-VideoS1.mp4MPEG-4 video, 21.2 MB	Video S1. The video showed the shape recovery process of TPV 60/40 from the “S”-type temporary shape triggering at 130°C.

The effect of rubber and plastic mass ratio on the compatibilized ethylene propylene diene monomer/polypropylene TPV with shape memory behavior

Abstract

CONFLICT OF INTEREST STATEMENT

Open Research

DATA AVAILABILITY STATEMENT

Supporting Information

REFERENCES

Citing Literature

References

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The effect of rubber and plastic mass ratio on the compatibilized ethylene propylene diene monomer/polypropylene TPV with shape memory behavior

Abstract

CONFLICT OF INTEREST STATEMENT

Open Research

DATA AVAILABILITY STATEMENT

Supporting Information

REFERENCES

Citing Literature

References

Related

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