Surface grafting stearic acid to the coupling agent on attapulgite: A reinforced filler in castor oil-based polyurethane coating
Shiping Wang
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Qingyuan Innovation Laboratory, Quanzhou, China
Contribution: Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - original draft (lead)
Search for more papers by this authorLushen Shen
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Contribution: Data curation (lead), Investigation (supporting)
Search for more papers by this authorHonglin Yang
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Contribution: Data curation (supporting), Investigation (supporting)
Search for more papers by this authorCorresponding Author
Guohui Cai
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Correspondence
Guohui Cai, Yingying Zhan, and Lilong Jiang, National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China Email: [email protected], [email protected], and [email protected]
Contribution: Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorGanchang Lei
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Contribution: Validation (equal)
Search for more papers by this authorLijuan Shen
College of Environmental Science and Engineering, Fujian Normal University, Fuzhou, China
Contribution: Validation (equal)
Search for more papers by this authorCorresponding Author
Yingying Zhan
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Qingyuan Innovation Laboratory, Quanzhou, China
Correspondence
Guohui Cai, Yingying Zhan, and Lilong Jiang, National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China Email: [email protected], [email protected], and [email protected]
Contribution: Funding acquisition (lead), Resources (supporting), Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Lilong Jiang
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Qingyuan Innovation Laboratory, Quanzhou, China
Correspondence
Guohui Cai, Yingying Zhan, and Lilong Jiang, National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China Email: [email protected], [email protected], and [email protected]
Contribution: Funding acquisition (lead), Resources (lead), Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorShiping Wang
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Qingyuan Innovation Laboratory, Quanzhou, China
Contribution: Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - original draft (lead)
Search for more papers by this authorLushen Shen
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Contribution: Data curation (lead), Investigation (supporting)
Search for more papers by this authorHonglin Yang
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Contribution: Data curation (supporting), Investigation (supporting)
Search for more papers by this authorCorresponding Author
Guohui Cai
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Correspondence
Guohui Cai, Yingying Zhan, and Lilong Jiang, National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China Email: [email protected], [email protected], and [email protected]
Contribution: Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorGanchang Lei
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Contribution: Validation (equal)
Search for more papers by this authorLijuan Shen
College of Environmental Science and Engineering, Fujian Normal University, Fuzhou, China
Contribution: Validation (equal)
Search for more papers by this authorCorresponding Author
Yingying Zhan
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Qingyuan Innovation Laboratory, Quanzhou, China
Correspondence
Guohui Cai, Yingying Zhan, and Lilong Jiang, National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China Email: [email protected], [email protected], and [email protected]
Contribution: Funding acquisition (lead), Resources (supporting), Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Lilong Jiang
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, China
Qingyuan Innovation Laboratory, Quanzhou, China
Correspondence
Guohui Cai, Yingying Zhan, and Lilong Jiang, National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China Email: [email protected], [email protected], and [email protected]
Contribution: Funding acquisition (lead), Resources (lead), Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorAbstract
Developing economic controlled-release fertilizers (CRFs) with superior performance is an ongoing and important research area. This work investigated the co-modification of acid-activated attapulgite (ac-AT) to optimize its surface properties for polyurethane (PU) composite applications, specifically in the coatings of CRFs. The modified ac-AT (MAT) rods were obtained through treatment with 2.0 wt.% KH-560 coupling agent and in-situ grafting with stearic acid (SA). Varying the addition amount of SA resulted in the synthesis of different MAT fillers. Along with the adjustment of the filling amount, the properties of the MAT/PU composites were controlled. Notably, applying 1.5 wt.% SA onto the KH-560 treated ac-AT produced MAT with a contact angle of 100.8°, enhancing hydrophobicity and dispersion within the PU matrix. Furthermore, at a filling amount of 9.0 wt.%, the MAT/PU composite exhibited the most favorable properties with a tensile strength of 2.37 MPa, making it the optimal coating for CRFs with 75% nutrient release within 46 days while the coating efficiency was 3.0 wt.%. This co-modification approach shows great potential in enhancing filler properties and promoting their application in organic coatings.
CONFLICT OF INTEREST STATEMENT
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Open Research
DATA AVAILABILITY STATEMENT
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| app54624-sup-0001-Supinfo.docxWord 2007 document , 4.9 MB | Data S1: Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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