Synthesis of modified graphene oxide and its improvement on flame retardancy of epoxy resin
Wenqian Wu
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorYiting Xu
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorHaiyang Wu
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorJinmei Chen
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorMin Li
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorTing Chen
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorJing Hong
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorCorresponding Author
Lizong Dai
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Correspondence to: L. Dai (E-mail: [email protected])Search for more papers by this authorWenqian Wu
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorYiting Xu
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorHaiyang Wu
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorJinmei Chen
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorMin Li
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorTing Chen
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorJing Hong
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Search for more papers by this authorCorresponding Author
Lizong Dai
Fujian Provincial Key Laboratory of Fire Retardant Materials, College of Materials, Xiamen University, Xiamen University, Xiamen, Fujian, 361005 People's Republic of China
Correspondence to: L. Dai (E-mail: [email protected])Search for more papers by this authorABSTRACT
In this work, the small molecule with double-phosphaphenanthrene structure was successfully grafted on the surface of graphene oxide (GO), which is called functionalized graphene oxide (FGO). The introduction of FGO improved the poor interfacial compatibility between graphene and epoxy matrix. And FGO could be used as the highly effective flame retardant. The thermogravimetric analysis results showed a significant improvement in the char yield of cured FGO/EP. When the content of FGO was 3 wt %, the limiting oxygen index value reached 30.4%. At the same time, the three-point bending and thermomechanical tests confirmed that the mechanical properties of the epoxy resin composites were improved. Based on the char analyses of SEM images and Raman spectroscopy, the flame retardant could promote the formation of a stable carbon layer. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 47710.
Supporting Information
| Filename | Description |
|---|---|
| app47710-sup-0001-Figures.docxWord 2007 document , 1.4 MB |
Figure S1 31P NMR spectrum of APTES-bisDOPO. Figure S2. FTIR spectra of GO (a), DOPO (b), APTES (c) and FGO (d). Figure S3. TGA and DTG curves of EP composites (nitrogen atmosphere (a and b), air atmosphere (c and d)). Figure S4. The digital photos of char residues after UL-94 tests. Figure S5. SEM images of the interior residual chars of EP-0 (a), EP-1 (b), EP-3 (c), EP-5 (d) and the exterior residual chars of EP-0 (e), EP-1 (f), EP-3 (g), EP-5 (h). Figure S6. SEM images of the interior residual chars of EP-1 (a), EP-3 (b), EP-5 (c) at higher magnification. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
REFERENCES
- 1Kong, Q. H.; Wu, T.; Zhang, J. H.; Wang, D. Y. Compos. Sci. Technol. 2018, 154, 136.
- 2Yang, X. T.; Guo, Y. Q.; Luo, X.; Zheng, N.; Ma, T. B.; Tan, J. J.; Lia, C. M.; Zhang, Q. Y.; Gu, J. W. Compos. Sci. Technol. 2018, 164, 59.
- 3Zhang, H. L.; Shi, C. J.; Han, J.; Yu, J. Y. Construct. Build Mater. 2013, 40, 1151.
- 4Wang, X.; Kalali, E. N.; Wang, D. Y. ACS Sustain. Chem. Eng. 2015, 3, 3281.
- 5Kalali, E. N.; Wang, X.; Wang, D. Y. J. Mater. Chem. A. 2015, 3, 6819.
- 6Wan, C. F.; Wen, B.; Dai, J. G.; Liu, J. X.; Liu, Y. Z. Materials. 2018, 11, 1174.
- 7Choi, J. R.; Rhee, K. Y.; Park, S. J. Compos. Part B. 2015, 80, 379.
- 8Liang, C. B.; Song, P.; Gu, H. B.; Ma, C.; Guo, Y. Q.; Zhang, H. Y.; Xu, X. J.; Gu, J. W. Compos. Part A. 2017, 102, 126.
- 9Xing, W.; Yang, W.; Yang, W. J.; Hu, Q. H.; Si, J. Y.; Lu, H. D.; Yang, B. H.; Song, L.; Hu, Y.; Yuen, R. K. K. ACS Appl. Mater. Interfaces. 2016, 8, 26266.
- 10Li, C.; Wan, J. T.; Kalali, E. N.; Fan, H.; Wang, D. Y. J. Mater. Chem. A. 2015, 3, 3471.
- 11Wicklein, B.; Kocjan, A.; Salazar-Alvarez, G.; Carosio, F.; Camino, G.; Antonietti, M.; Bergström, L. Nat. Nanotechnol. 2015, 10, 277.
- 12Dittrich, B.; Wartig, K. A.; Mülhaupt, R.; Schartel, B. Polymers. 2014, 6, 2875.
- 13Yuan, F. Y.; Zhang, H. B.; Li, X. F.; Ma, H. L.; Li, X. Z.; Yu, Z. Z. Carbon. 2014, 68, 653.
- 14Gu, J. W.; Liang, C. B.; Zhao, X. M.; Gan, B.; Qiu, H.; Guo, Y. Q.; Yang, X. T.; Zhang, Q. Y.; Wang, D. Y. Compos. Sci. Technol. 2017, 139, 83.
- 15Liu, S.; Fang, Z. P.; Yan, H. Q.; Wang, H. RSC Adv. 2016, 6, 5288.
- 16Hontorialucas, C.; Lopezpeinado, A. J.; Lopezgonzalez, J. D. D.; Rojascervantes, M. L.; Martinaranda, R. M. Carbon. 1995, 33, 1585.
- 17Ruan, K. P.; Guo, Y. Q.; Tang, Y. S.; Zhang, Y. L.; Zhang, J. N.; He, M. K.; Kong, J.; Gu, J. W. Compos. Commun. 2018, 10, 68.
- 18Guo, Y. Q.; Xu, G. J.; Yang, X. T.; Ruan, K. P.; Ma, T. B.; Zhang, Q. Y.; Gu, J. W.; Wu, Y. L.; Liu, H.; Guo, Z. H. J. Mater. Chem. C. 2018, 6, 3004.
- 19Wang, R.; Zhuo, D. X.; Weng, Z. X.; Wu, L. X.; Cheng, X. Y.; Zhou, Y.; Wang, J. L.; Xuan, B. W. J. Mater. Chem. A. 2015, 3, 9826.
- 20Yu, B.; Shi, Y. Q.; Yuan, B. H.; Qiu, S. L.; Xing, W. Y.; Hu, W. Z.; Song, L.; Lo, S. M.; Hu, Y. J. Mater. Chem. A. 2015, 3, 8034.
- 21Shi, Y. Q.; Fu, T.; Xu, Y. J.; Li, D. F.; Wang, X. L.; Wang, Y. Z. Chem. Eng. J. 2018, 354, 208.
- 22Van der Veen, I.; de Boer, J. Chemosphere. 2012, 88, 1119.
- 23Papachlimitzou, A.; Barber, J. L.; Losada, S.; Bersuder, P.; Law, R. J. J. Chromatogr. A. 2012, 1219, 15.
- 24Salmeia, K. A.; Gaan, S. Polym. Degrad. Stabil. 2014, 113, 119.
- 25Carja, I. -D.; Serbezeanu, D.; Vlad-Bubulac, T.; Hamciuc, C.; Coroaba, A.; Lisa, G.; L'opez, C. G.; Soriano, M. F.; P'erez, V. F.; Romero S'anchez, M. D. J. Mater. Chem. A. 2014, 2, 16230.
- 26Schartel, B.; Braun, U.; Balabanovich, A. I.; Artner, J.; Ciesielski, M.; Döring, M.; Perez, R. M.; Sandler, J. K. W.; Altstädt, V. Eur. Polym. J. 2008, 44, 704.
- 27Zhang, W. C.; Li, X. M.; Yang, R. J. Polym. Degrad. Stabil. 2011, 96, 2167.
- 28Song, S. Q.; Ma, J. J.; Cao, K.; Chang, G. J.; Huang, Y. W.; Yang, J. X. Polym. Degrad. Stabil. 2014, 99, 43.
- 29Cherkasov, R. A.; Galkin, V. I. Russ. Chem. Rev. 1998, 67, 857.
10.1070/RC1998v067n10ABEH000421 Google Scholar
- 30Zhang, Y.; Zhao, Y.; Yang, B.; Zhu, C.; Wei, Y.; Tao, L. Polym. Chem. 2014, 5, 1857.
- 31Wan, Y. J.; Gong, L. X.; Tang, L. C.; Wu, L. B.; Jiang, J. X. Compos. Part A. 2014, 64, 79.
- 32Wang, X.; Xing, W. Y.; Zhang, P.; Song, L.; Yang, H. Y.; Hu, Y. Compos. Sci. Technol. 2012, 72, 737.
- 33Li, Z.; Wang, R. G.; Young, R. J.; Deng, L. B.; Yang, F.; Hao, L. F.; Jiao, W. C.; Liu, W. B. Polymer. 2013, 54, 6437.
- 34Yu, Z. X.; Lv, L.; Ma, Y.; Di, H. H.; He, Y. RSC Adv. 2016, 6, 18217.
- 35Zhang, W. C.; Yang, R. J. J. Appl. Polym. Sci. 2011, 122, 3383.
- 36Liu, C.; Chen, T.; Yuan, C. H.; Song, C. F.; Chang, Y.; Chen, G. R.; Xu, Y. T.; Dai, L. Z. J. Mater. Chem. A. 2016, 4, 3462.
- 37Shen, J. F.; Hu, Y. Z.; Shi, M.; Lu, X.; Qin, C.; Li, C.; Ye, M. X. Chem. Mater. 2009, 21, 3514.
- 38Rao, C. N. R.; Sood, A. K.; Subrahmanyam, K. S.; Govindaraj, A. Angew. Chem. Int. Ed. 2009, 48, 7752.
- 39Kudin, K. N.; Ozbas, B.; Schniepp, H. C.; Prud'homme, R. K.; Aksay, I. A.; Car, R. Nano Lett. 2008, 8, 36.
- 40Liao, S. H.; Liu, P. L.; Hsiao, M. C.; Teng, C. C.; Wang, C. A.; Ger, M. D.; Chiang, C. L. Ind. Eng. Chem. Res. 2012, 51, 4573.
- 41Lee, C. Y.; Bae, J. H.; Kim, T. Y.; Chang, S. H.; Kim, S. Y. Compos. Part A. 2015, 75, 11.
- 42Wang, Z. H.; Wei, P.; Qian, Y.; Liu, J. P. Compos. Part B. 2014, 60, 341.
- 43Chen, W.; Liu, Y. S.; Xu, C. G.; Liu, Y.; Wang, Q. RSC Adv. 2017, 7, 39786.
- 44Liu, F. D.; Wu, L.; Song, Y. J.; Xia, W. G.; Guo, K. K. RSC Adv. 2015, 5, 45987.
- 45Yang, X. T.; Tang, L.; Guo, Y. Q.; Liang, C. B.; Zhang, Q. Y.; Kou, K. C.; Gu, J. W. Compos. Part A. 2017, 101, 237.
- 46Gu, J. W.; Xu, S.; Zhuang, Q.; Tang, Y. S.; Kong, J. IEEE T. Dielect. El. In. 2017, 24, 784.
- 47Wang, X.; Hu, Y.; Song, L.; Xing, W. Y.; Lu, H. D. A.; Lv, P.; Jie, G. X. Polymer. 2010, 51, 2435.
- 48Han, Y. Q.; Wu, Y.; Shen, M. X.; Huang, X. L.; Zhu, J. J.; Zhang, X. G. J. Mater. Sci. 2013, 48, 4214.
- 49Shieh, J. Y.; Wang, C. S. Polymer. 2001, 42, 7617.
- 50Ma, T. T.; Guo, C. G. J. Anal. Appl. Pyrol. 2017, 124, 239.
- 51Wang, X.; Kalali, E. N.; Wan, J. T.; Wang, D. Y. Prog. Polym. Sci. 2017, 69, 22.
- 52Wu, H. Y.; Li, Y. T.; Zeng, B. R.; Chen, G. R.; Wu, Y. Z.; Chen, T.; Dai, L. Z. React. Funct. Polym. 2018, 131, 89.
- 53Guo, Y. Q.; Bao, C. L.; Song, L.; Yuan, B. H.; Hu, Y. Ind. Eng. Chem. Res. 2011, 50, 7772.
- 54Gudarzi, M. M.; Sharif, F. Express Polym. Lett. 2012, 6, 1017.
- 55Lee, C.; Wei, X. D.; Kysar, J. W.; Hone, J. Science. 2008, 321, 385.
- 56Zhang, X. Q.; Fan, X. Y.; Li, H. Z.; Yan, C. J. Mater. Chem. 2012, 22, 24081.
- 57Tang, L. C.; Wan, Y. J.; Yan, D.; Pei, Y. B.; Zhao, L.; Li, Y. B.; Wu, L. B.; Jiang, J. X.; Lai, G. Q. Carbon. 2013, 60, 16.
- 58Zaman, I.; Kuan, H. C.; Meng, Q. S.; Michelmore, A.; Kawashima, N.; Pitt, T.; Zhang, L. Q.; Gouda, S.; Luong, L.; Ma, J. Adv. Funct. Mater. 2012, 22, 2735.
- 59Zaman, I.; Phan, T. T.; Kuan, H. C.; Meng, Q. S.; Bao La, L. T.; Luong, L.; Youssf, O.; Ma, J. Polymer. 2011, 52, 1603.
- 60Bao, C. L.; Guo, Y. Q.; Song, L.; Kan, Y. C.; Qian, X. D.; Hu, Y. J. Mater. Chem. 2011, 21, 13290.
