Volume 137, Issue 1 47601

Article

Intumescent fire-retardant coatings for plastics based on poly(vinylphosphonic acid): Improving water resistance with comonomers

Katherine Williams,

Katherine Williams

Institute for Materials Research and Innovation, University of Bolton, Deane Road, Bolton BL35AB, UK

Exova Warringtonfire, Holmsfield Rd, Warrington WA1 2D, UK

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John R. Ebdon,

John R. Ebdon

orcid.org/0000-0003-4176-3912

Institute for Materials Research and Innovation, University of Bolton, Deane Road, Bolton BL35AB, UK

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Baljinder K. Kandola,

Corresponding Author

Baljinder K. Kandola

[email protected]

orcid.org/0000-0002-3621-3724

Institute for Materials Research and Innovation, University of Bolton, Deane Road, Bolton BL35AB, UK

Correspondence to: B. K. Kandola (E-mail: [email protected])Search for more papers by this author

Katherine Williams,

Katherine Williams

Institute for Materials Research and Innovation, University of Bolton, Deane Road, Bolton BL35AB, UK

Exova Warringtonfire, Holmsfield Rd, Warrington WA1 2D, UK

Search for more papers by this author

John R. Ebdon,

John R. Ebdon

orcid.org/0000-0003-4176-3912

Institute for Materials Research and Innovation, University of Bolton, Deane Road, Bolton BL35AB, UK

Search for more papers by this author

Baljinder K. Kandola,

Corresponding Author

Baljinder K. Kandola

[email protected]

orcid.org/0000-0002-3621-3724

Institute for Materials Research and Innovation, University of Bolton, Deane Road, Bolton BL35AB, UK

Correspondence to: B. K. Kandola (E-mail: [email protected])Search for more papers by this author

First published: 11 February 2019

https://doi.org/10.1002/app.47601

Citations: 13

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ABSTRACT

Coatings based on the in situ photopolymerization of vinyl phosphonic acid (VPA) with triallyl cyanurate as a crosslinking agent are shown to be effective not only for fire-protecting glass fiber-reinforced epoxy resin (GRE) composites but also poly(methyl methacrylate) (PMMA), a typical meltable and flammable thermoplastic. Dry adhesion of polyVPA coatings to PMMA surfaces is excellent but, as with coatings on GRE, adhesion following water-soak tests is poor. Copolymerizing VPA with more hydrophobic monomers improves wet adhesion, albeit with some impairment of fire performance, with copolymers of VPA and acrylonitrile giving the best results. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 47601.

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Volume137, Issue1

Special Issue:Flame Retardant Polymers and Composites

January 5, 2020

47601

Intumescent fire-retardant coatings for plastics based on poly(vinylphosphonic acid): Improving water resistance with comonomers

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Intumescent fire-retardant coatings for plastics based on poly(vinylphosphonic acid): Improving water resistance with comonomers

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