Size-controlled gold nanoparticles inside polyacrylamide microgels
M. Díaz
Departamento de Ciencias Tecnológicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorA. Barrera
Departamento de Ciencias Básicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorS. López-Cuenca
Instituto Tecnológico Superior de Tequila, Joel Magallanes Rubio 501, Col. Lomas del Paraíso, 46400 Tequila, Jalisco, Mexico
Search for more papers by this authorS. Y. Martínez-Salazar
Departamento de Ciencias Básicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorM. Rabelero
Departamento de Ingeniería Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, 44430 Guadalajara, Jalisco, Mexico
Search for more papers by this authorI. Ceja
Departamento de Física, Universidad de Guadalajara, Boulevard M. García Barragán 1451, 44430 Guadalajara, Jalisco, Mexico
Search for more papers by this authorV. V. A. Fernández
Departamento de Ciencias Tecnológicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorCorresponding Author
J. Aguilar
Departamento de Ciencias Tecnológicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Correspondence to: J. Aguilar (E-mail: [email protected])Search for more papers by this authorM. Díaz
Departamento de Ciencias Tecnológicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorA. Barrera
Departamento de Ciencias Básicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorS. López-Cuenca
Instituto Tecnológico Superior de Tequila, Joel Magallanes Rubio 501, Col. Lomas del Paraíso, 46400 Tequila, Jalisco, Mexico
Search for more papers by this authorS. Y. Martínez-Salazar
Departamento de Ciencias Básicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorM. Rabelero
Departamento de Ingeniería Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, 44430 Guadalajara, Jalisco, Mexico
Search for more papers by this authorI. Ceja
Departamento de Física, Universidad de Guadalajara, Boulevard M. García Barragán 1451, 44430 Guadalajara, Jalisco, Mexico
Search for more papers by this authorV. V. A. Fernández
Departamento de Ciencias Tecnológicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Search for more papers by this authorCorresponding Author
J. Aguilar
Departamento de Ciencias Tecnológicas, Universidad de Guadalajara, Avenida Universidad 1115, 47820, Ocotlán, Jalisco, 47820 Mexico
Correspondence to: J. Aguilar (E-mail: [email protected])Search for more papers by this authorABSTRACT
Gold nanoparticles (AuNPs) of different sizes were synthesized into a crosslinked network of polyacrylamide (PAAm) microgels. PAAm was prepared by means of semicontinuous inverse heterophase polymerization under monomer-starving conditions with a z-average particle size of 384 ± 18 nm. AuNPs with controlled size were obtained by a reduction reaction of Au+3 to Au0 from a gold(III) chloride trihydrate (HAuCl4) solution inside microgel the crosslinked network (AuNP-PAAm). The reduction reaction was verified for 2 h by ultraviolet–visible spectroscopy (UV–vis). AuNP–PAAm exhibited a particle size between 288 ± 12 and 230 ± 15 nm at HAuCl4 concentrations of 0.4 and 1.3 mM, respectively. The AuNP–PAAms were observed by transmission electron microscopy, and their sizes were determined to be 19 ± 2 nm (1.3 mM) and 17 ± 2 nm (1.1 mM). With UV–vis spectroscopy, we detected the formation of AuNPs at a wavelength of 552 nm, and with X-ray diffraction analysis, we proved that the crystal arrangement was face-centered cubic. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43560.
Supporting Information
Additional Supporting Information may be found in the online version of this article
| Filename | Description |
|---|---|
| app43560-sup-0001-suppinfo.pdf7.5 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
REFERENCES
- 1 Haruta, M.; Yamada, N.; Kobayashi, T.; Lijima, T. J. Catal. 1989, 115, 301.
- 2 Panigrahi, S.; Basu, S.; Praharaj, S.; Pande, S.; Jana, S.; Pal, A.; Kumar, S.; Pal, T. J. Phys. Chem. C 2007, 111, 4596.
- 3 Stratakis, M.; García, H. Chem. Rev. 2012, 112, 4469.
- 4 Theodoros, S.; Loannis, L.; Konstantinos, L. Tetrahedron 2013, 69, 4612.
- 5 Petros, G.; Manolis, S.; Loannis, L. Catal. Commun. 2013, 36, 48.
- 6
Ramírez, J.;
Sanaú, M.;
Fernández, E. Angew. Chem. Int. Ed. 2008, 120, 5272.
10.1002/ange.200800541 Google Scholar
- 7 Shanahan, A. E.; Sullivan, J. A.; McNamara, M.; Byrne, H. J. New Carbon Mater. 2011, 26, 347.
- 8 Gross, G. M.; Nelson, D. A.; Grate, J. W.; Synovec, R. E. Anal. Chem. 2003, 75, 4558.
- 9 Guidelli, E. J.; Ramos, A. P.; Zaniquelli, M. E. D.; Nicolucci, P.; Baffa, O. ACS Appl. Mater. Interfaces 2012, 4, 5844.
- 10 Chen, L.; Lu, W.; Wang, X.; Chen, L. Sens. Actuators B 2013, 182, 482.
- 11 Mingjian, Y.; Yongjun, L. I.; Huibiao, L. I. U.; Yuliang, L. I. Sci. China Ser. B 2009, 52, 715.
- 12 Thakor, A. S.; Jokerst, J.; Zavaleta, C.; Massoud, T. F.; Gambhir, S. S. Nano Lett. 2011, 11, 4029.
- 13 Hayashi, A.; Naseri, A.; Pennesi, M. E.; de Juan, E., Jr. Jpn. J. Ophthalmol. 2009, 53, 249.
- 14 Krpetic, Z.; Porta, F.; Scarì, G. Gold Bull. 2006, 39, 66.
- 15 Yun, G. E.; Bin, K. Sci. China Ser. E 2011, 54, 2358.
- 16 Jana, S.; Salehi-Khojin, A.; Zhong, W. H.; Chen, H.; Liu, X.; Huo, Q. Solid State Ionics 2007, 178, 1180.
- 17 Kawasaki, H.; Nishimura, K.; Arakawa, R. J. Phys. Chem. C 2007, 111, 2683.
- 18 Prasad, B. L. V.; Arumugam, S. K.; Bala, T.; Sastry, M. Langmuir 2005, 21, 822.
- 19 Calandra, P.; Giordano, C.; Longo, A.; Turco, L. V. Mater. Chem. Phys. 2006, 98, 494.
- 20 Tang, J.; Huang, J.; Man, S. Q. Spectrochim. Acta A 2013, 103, 349.
- 21 Turkevich, J. Gold Bull. 1985, 18, 86.
- 22 Duan, H.; Cui, H.; Zhang, Z.; Liu, B.; Guo, J.; Wang, W. J. Phys. Chem. C 2007, 111, 4561.
- 23 Liu, Y.; Male, K. B.; Bouvrette, P.; Luong, J. H. T. Chem. Mater. 2003, 15, 4172.
- 24 Wu, H.; Ji, X.; Zhao, L.; Yang, S.; Xie, R.; Yang, W. Colloids Surf. A 2012, 415, 174.
- 25 Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. J. Chem. Soc. Chem. Commun. 1994, 7, 801.
- 26 Newman, J. D. S.; Blanchard, G. J. Langmuir 2006, 22, 5882.
- 27 Kumar, A.; Mandal, S.; Selvakannan, P. R.; Pasricha, R.; Mandale, A. B.; Sastry, M. Langmuir 2003, 19, 6277.
- 28 Sahiner, N. Prog. Polym. Sci. 2013, 38, 1329.
- 29 Yildiz, S.; Aktas, N.; Sahiner, N. Int. J. Hydrogen Energy 2014, 39, 14690.
- 30 Yildiz, S.; Sahiner, M.; Sahiner, N. Eur. Polym. J. 2015, 70, 66.
- 31 Bengzon-Tan, N. P.; Lee, C. H.; Chen, L.; Ho, K. M.; Lu, Y.; Ballauff, M.; Lei, P. Polymer 2015, 76, 271.
- 32 Lu, Y.; Proch, S.; Schrinner, M.; Drechsler, M.; Kempe, R.; Ballauff, M. J. Matter Chem. 2009, 19, 3955.
- 33 Wu, S.; Kaiser, J.; Drechsler, M.; Ballauf, M.; Lu, Y. Colloid Polym. Sci. 2013, 291, 231.
- 34 Thomas, V.; Namdeo, M.; Mohan, Y. M.; Bajpai, S. K.; Bajpai, M. J. Macromol. Sci. Pure Appl. Chem. 2007, 45, 107.
- 35 Sugunan, A.; Thanachayanont, C.; Dutta, J.; Hilborn, J. G. Sci. Technol. Adv. Mater. 2005, 6, 335.
- 36 Satarkar, N. S.; Hilt, J. Z. J. Controlled Release 2008, 130, 246.
- 37 Wong, J. E.; Gaharwar, A. K.; Müller-Schulet, D.; Dahadur, D.; Richtering, W. J. Colloid Interface Sci. 2008, 324, 47.
- 38 Zhang, J.; Xu, S.; Kumacheva, E. J. Am. Chem. Soc. 2004, 126, 7908.
- 39 Yousif, A. M. J. Polym. Res. 2013, 20, 33.
- 40 Zielinska, A. K.; Sawosz, E.; Grodzik, M.; Chwalibog, A.; Kamaszewski, M. In Annals of Warsaw University of Life Sciences—SGGW, Animal Science; T Kaleta., Ed.; Warsaw University of Life Sciences Press: Warsaw, 2009; Vol. 46, p 249.
- 41 Sahiner, N.; Yu, H.; Tan, G.; He, J.; John, V. T.; Blake, D. A. ACS Appl. Mater. Interfaces 2012, 4, 163.
- 42 Aguilar, J.; Moscoso, F.; Ríos, O.; Ceja, I.; Sánchez, J. C.; Bautista, F.; Puig, J. E.; Fernández, V. V. A. J. Macromol. Sci. Pure Appl. Chem. 2014, 51, 412.
- 43 Silva, J. M.; Ortega-Gudiño, P.; Rabelero, M.; Sánchez-Díaz, J. C.; Guerrero-Ramírez, L. G.; Puig, J. E. J. Macromol. Sci. Pure Appl. Chem. 2013, 50, 596.
- 44 Song, Y.; Li, Z.; Wang, L.; Yao, Y.; Chen, Ch.; Cui, K. Microsc. Res. Tech. 2008, 71, 409.
- 45 Fernandez, V. V. A.; Tepale, N.; Sánchez-Díaz, J. C.; Mendizábal, E.; Puig, J. E.; Soltero, J. F. A. Colloid Polym. Sci. 2006, 284, 387.
- 46 Suh, J. S.; Michaelian, K. H. J. Raman Spectrosc. 1987, 18, 409.
- 47 Ahern, A. M.; Garrell, R. L. Langmuir 1988, 4, 1162.
- 48 Rapp, T. L.; Kowalchyk, W. K.; Davis, K. L.; Todd, E. A.; Liu, K. L.; Morris, M. D. Anal. Chem. 1992, 64, 2434.
- 49 Li, C.; Cai, Y.; Zhu, Y.; Ma, M.; Zheng, W.; Zhu, J. J. Nanopart. Res. 2013, 15, 1922.
- 50 Zhu, Y.; Qian, Y.; Li, W.; Zhang, M. Chem. Commun. 1997, 1081.
- 51 Zhu, J. F.; Zhu, Y. J.; Ma, M. G.; Yang, L. X.; Gao, L. J. Phys. Chem. C 2007, 111, 3920.
- 52 Zhao, Y.-L.; Chen, Y.; Wang, M.; Liu, Y. Org. Lett. 2006, 8, 1267.
Citing Literature
July 5, 2016
