Preparation and characterization of UV-cured hybrid coatings by triethoxysilane-modified dimethacrylate based on bisphenol-s epoxy
Chunguang Li
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorJue Cheng
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorFeng Yang
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorWenkai Chang
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorCorresponding Author
Jun Nie
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China===Search for more papers by this authorChunguang Li
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorJue Cheng
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorFeng Yang
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorWenkai Chang
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorCorresponding Author
Jun Nie
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China===Search for more papers by this authorAbstract
Novel hybrid oligomers based on a UV-curable bisphenol-S epoxy dimethacrylate (DBSMA) were synthetized. DBSMA was modified with various amount of (3-isocyanatopropyl)triethoxysilane coupling agent. The modification degree of the hybrid oligomer was varied from 0 to70 wt %. The photopolymerization kinetics was monitored by a real-time infrared spectroscopy. The conversion and rate of hybrid coatings increased with the increase in modification degree. UV-curable, hard, and transparent organic–inorganic hybrid coatings were prepared. They were performed by the analyses of various properties such as surface and mechanical properties. Results from the mechanical measurements showed that the properties of hybrid coatings improved with the increase in modification degree. The thermal behavior of coatings was also investigated. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
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