Elaboration and thermal analysis of nanocomposites based on poly(methyl methacrylate-co-4-vinylpyridine) and Maghnia bentonite

Kamal Ouaad

Université des Sciences et de la Technologìe Houari Boumediene, Laboratoire des Matériaux Polymères, Faculté de Chimie, BP 32 El-Alia, Bab-Ezzouar 16111, Algiers, Algeria

Département de Chimie, Université M'Hamed Bougara, Faculté des Sciences, Avenue de l'Indépendance, 35000, Boumerdès, Algeria

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Saïd Djadoun,

Corresponding Author

Saïd Djadoun

[email protected]

Université des Sciences et de la Technologìe Houari Boumediene, Laboratoire des Matériaux Polymères, Faculté de Chimie, BP 32 El-Alia, Bab-Ezzouar 16111, Algiers, Algeria

Université des Sciences et de la Technologìe Houari Boumediene, Laboratoire des Matériaux Polymères, Faculté de Chimie, BP 32 El-Alia, Bab-Ezzouar 16111, Algiers, Algeria===Search for more papers by this author

Kamal Ouaad,

Kamal Ouaad

Université des Sciences et de la Technologìe Houari Boumediene, Laboratoire des Matériaux Polymères, Faculté de Chimie, BP 32 El-Alia, Bab-Ezzouar 16111, Algiers, Algeria

Département de Chimie, Université M'Hamed Bougara, Faculté des Sciences, Avenue de l'Indépendance, 35000, Boumerdès, Algeria

Search for more papers by this author

Saïd Djadoun,

Corresponding Author

Saïd Djadoun

[email protected]

Université des Sciences et de la Technologìe Houari Boumediene, Laboratoire des Matériaux Polymères, Faculté de Chimie, BP 32 El-Alia, Bab-Ezzouar 16111, Algiers, Algeria

First published: 03 January 2013

https://doi.org/10.1002/app.38915

Citations: 1

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Abstract

Nanocomposites based on an organically modified bentonite, from Maghnia Algeria (OBT) and a copolymer of methyl methacrylate with 4-vinylpyridine (PMM4VP) synthesized in dioxan at room temperature using a neutral Ni(II)α-benzoinoxime complex as a single component initiator, were elaborated via solution intercalation method and characterized by several techniques. X-ray diffraction and transmission electron microscopy investigations indicate that mainly exfoliated and intercalated PMM4VP/OBT nanocomposites were elaborated and that the degree of exfoliation decreases with an increase of the OBT loading. Thermal analyses of these nanocomposites compared with their virgin copolymer confirmed a significant improvement of their thermal stability as evidenced by an increase of 28°C in their onset degradation temperatures. In addition, differential scanning calorimetry displayed an increase in the range of 12–18°C in their glass transition temperatures relative to their virgin copolymer. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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Volume129, Issue4

15 August 2013

Pages 2029-2035

Elaboration and thermal analysis of nanocomposites based on poly(methyl methacrylate-co-4-vinylpyridine) and Maghnia bentonite

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Elaboration and thermal analysis of nanocomposites based on poly(methyl methacrylate-co-4-vinylpyridine) and Maghnia bentonite

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