Volume 129, Issue 4 pp. 1952-1958

Article

Selective recognition of beta-cypermethrin by molecularly imprinted polymers based on magnetite yeast composites

Corresponding Author

Wei-Sheng Guan

[email protected]

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China===Search for more papers by this author

Jun-Ru Lei,

Jun-Ru Lei

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Xu Wang,

Xu Wang

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Ya Zhou,

Ya Zhou

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Chen-Chen Lu,

Chen-Chen Lu

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Shao-Fang Sun,

Shao-Fang Sun

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Wei-Sheng Guan,

Corresponding Author

Wei-Sheng Guan

[email protected]

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China===Search for more papers by this author

Jun-Ru Lei,

Jun-Ru Lei

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Xu Wang,

Xu Wang

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Ya Zhou,

Ya Zhou

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Chen-Chen Lu,

Chen-Chen Lu

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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Shao-Fang Sun,

Shao-Fang Sun

Ministry of Education, College of the Environmental Science and Engineering, Chang'an University, Xi'an 710054, People's Republic of China

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First published: 03 January 2013

https://doi.org/10.1002/app.38879

Citations: 9

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Abstract

Magnetic nanoparticles were attached to yeast by co-precipitation reaction of FeCl₃·6H₂O and FeCl₂·4H₂O. Then, based on magnetite yeast composites (M@Y), the magnetic molecularly imprinted polymers (MMIPs) were synthesized for the selective recognition of beta-cypermethrin (PP₃₂₁). MMIPs were characterized by scanning electron microscopy, X-ray diffraction, vibrating sample magnetometer, Fourier transform infrared analysis, thermogravimetric analysis, and elemental analysis. MMIPs exhibited uniform morphology and magnetic property (Ms = 17.87 emu/g) and thermal stability. Batch mode adsorption studies were carried out to investigate the specific adsorption equilibrium, kinetics, and selective recognition. The Langmuir isotherm model was fitted to the equilibrium data slightly better than the Freundlich model, and the adsorption capacity of MMIPs was 39.64 mg/g at 298 K. The kinetic properties of MMIPs were well described by the pseudo-second-order equation. Hydrogen bonds between methacrylic acid and PP₃₂₁ were mainly responsible for the adsorption mechanism. The MMIPs prepared were applied to the separation of PP₃₂₁ from experimental samples successfully. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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Volume129, Issue4

15 August 2013

Pages 1952-1958

Selective recognition of beta-cypermethrin by molecularly imprinted polymers based on magnetite yeast composites

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Selective recognition of beta-cypermethrin by molecularly imprinted polymers based on magnetite yeast composites

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