Volume 120, Issue 6 pp. 3460-3468

Morphology, crystallization, and mechanical properties of poly(ethylene terephthalate)/multiwalled carbon nanotubes composites

Zhiguo Zhu

Corresponding Author

Zhiguo Zhu

Beijing Key Laboratory of Clothing Materials R&D and Assessment, Beijing 100029, People's Republic of China

Department of Materials Science and Engineering, Beijing Institute of Clothing Technology, Beijing 100029, People's Republic of China

Beijing Key Laboratory of Clothing Materials R&D and Assessment, Beijing 100029, People's Republic of China===Search for more papers by this author
Rui Wang

Rui Wang

Beijing Key Laboratory of Clothing Materials R&D and Assessment, Beijing 100029, People's Republic of China

Department of Materials Science and Engineering, Beijing Institute of Clothing Technology, Beijing 100029, People's Republic of China

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Zhenfeng Dong

Zhenfeng Dong

Beijing Key Laboratory of Clothing Materials R&D and Assessment, Beijing 100029, People's Republic of China

Department of Materials Science and Engineering, Beijing Institute of Clothing Technology, Beijing 100029, People's Republic of China

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Xiuqin Huang

Xiuqin Huang

Beijing Key Laboratory of Clothing Materials R&D and Assessment, Beijing 100029, People's Republic of China

Department of Materials Science and Engineering, Beijing Institute of Clothing Technology, Beijing 100029, People's Republic of China

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Dasheng Zhang

Dasheng Zhang

Beijing Key Laboratory of Clothing Materials R&D and Assessment, Beijing 100029, People's Republic of China

Department of Materials Science and Engineering, Beijing Institute of Clothing Technology, Beijing 100029, People's Republic of China

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First published: 14 February 2011
Citations: 19

Abstract

Poly(ethylene terephthalate)/multiwalled carbon nanotubes (PET/MWCNTs) with different MWCNTs loadings have been prepared by in situ polymerization of ethylene glycol (EG) containing dispersed MWCNTs and terephthalic acid (TPA). From scanning electronic microscopy images of nanocomposites, it can be clearly seen that the PET/MWCNTs composites with low-MWCNTs contents (0.2 and 0.4 wt %) get better MWCNTs dispersion than analogous with high-tube loadings (0.6 and 0.8 wt %). The nonisothermal crystallization kinetics was analyzed by differential scanning calorimetry using Mo kinetics equation, and the results showed that the incorporation of MWCNTs accelerates the crystallization process obviously. Mechanical testing shows that, in comparison with neat PET, the Young's modulus and the yield strength of the PET nanocomposites with incorporating 0.4 wt % MWCNTs are effectively improved by about 25% and 15%, respectively. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

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