Volume 116, Issue 1 pp. 355-365

New polymers from plant oil derivatives and styrene-maleic anhydride copolymers

Cem Öztürk,

Cem Öztürk

Boğaziçi University, Department of Chemistry and Polymer Research Center, Bebek, Istanbul 34342, Turkey

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Selim H. Küsefoğlu,

Corresponding Author

Selim H. Küsefoğlu

[email protected]

Boğaziçi University, Department of Chemistry and Polymer Research Center, Bebek, Istanbul 34342, Turkey

Boğaziçi University, Department of Chemistry and Polymer Research Center, Bebek, Istanbul 34342, Turkey===Search for more papers by this author

Cem Öztürk,

Cem Öztürk

Boğaziçi University, Department of Chemistry and Polymer Research Center, Bebek, Istanbul 34342, Turkey

Search for more papers by this author

Selim H. Küsefoğlu,

Corresponding Author

Selim H. Küsefoğlu

[email protected]

Boğaziçi University, Department of Chemistry and Polymer Research Center, Bebek, Istanbul 34342, Turkey

Boğaziçi University, Department of Chemistry and Polymer Research Center, Bebek, Istanbul 34342, Turkey===Search for more papers by this author

First published: 01 December 2009

https://doi.org/10.1002/app.31609

Citations: 11

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Abstract

In this study, styrene maleic anhydride copolymer (SMA2000, Styrene : Maleic Anhydride 2 : 1) is grafted and/or crosslinked with epoxidized methyl oleate, epoxidized soybean oil, methyl ricinoleate (MR), castor oil (CO), and soybean oil diglyceride. Base catalyzed epoxy-anhydride and alcohol-anhydride polyesters were synthesized by using the anhydride on SMA, the epoxy or secondary alcohol groups on the triglyceride based monomers. The characterizations of the products were done by DMA, TGA, and IR spectroscopy. SMA-epoxidized soy oil and SMA-CO polymers are crosslinked rigid infusible polymers. SMA-epoxidized soy oil and SMA-CO showed T_g's at 70 and 66°C, respectively. Dynamic moduli of the two polymers were 11.73 and 3.34 Mpa respectively. SMA-epoxidized methyl oleate, poly[styrene-co-(maleic anhydride)]-graft-(methyl ricinoleate), and SMA-soy oil diglyceride polymers were soluble and thermoplastic polymers and were characterized by TGA, GPC, DSC, NMR, and IR spectroscopy. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010

References

1 Crank, M.; Patel, M.; Marscheider-Weidemann, F.; Schleich, J.; HU'sing, B.; Angerer, G.; Wolf, O. European Commission—Institute for Prospective Technological Studies, Seville, EUR 22103 EN, 2005.
Google Scholar
2 Stowers, M. D. Presented at the Iowa Biotech Association's Annual Conference; Des Moines, Iowa, 2004.
Google Scholar
3A survey of recent chemical price trends—the potential impact of rising petrochemical prices on soy use for industrial applications, Available at: http://www.soynewuses.com/down loads/PriceTrendSurvey.pdf. Accessed 2009.
Google Scholar
4 Rios, L. A. Ph.D. Dissertation, Rheinisch-Westfälischen Technischen Hochschule, Aachen, Germany, 2003.
Google Scholar
5 Güner, F. S.; Yağci, Y.; Erciyes, A. T. Prog Polym Sci 2006, 31, 633.
10.1016/j.progpolymsci.2006.07.001
CAS Web of Science® Google Scholar
6 Baumann, H.; Buhler, M.; Fochem, H.; Hirsinger, F.; Zoebelein, H.; Falbe, J. Angew Chem Int Ed Eng 1988, 27, 41.
10.1002/anie.198800411
Web of Science® Google Scholar
7 Wool, R. U.S. Pat. 6,121,398, ( 2000).
Google Scholar
8 Frische, R. U.S. Pat. 5,302,670, ( 1994).
Google Scholar
9Market opportunity summary, soy-based thermoset plastics, Available at: http://www.soynewuses.com/downloads/Price TrendSurvey.pdf. Accessed on March 2008; p 2.
Google Scholar
10 Warth, H.; Mulhaupt, R.; Hoffmann, B.; Lawsona, S. Die Angew Makromol Chem 1997, 249, 79.
10.1002/apmc.1997.052490106
CAS Web of Science® Google Scholar
11 Boquillon, N.; Fringant, C. Polymer 2000, 41, 8603.
10.1016/S0032-3861(00)00256-1
CAS Web of Science® Google Scholar
12 Gerbase, A. E.; Petzhold, C. L.; Costa, A. P. O. J Am Oil Chem Soc 2002, 79, 797.
10.1007/s11746-002-0561-z
CAS Web of Science® Google Scholar
13 Miyagawa, H.; Mohanty, A. K.; Misra, M.; Drzal, L. T. Macromol Mater Eng 2004, 289, 629.
10.1002/mame.200400004
CAS Web of Science® Google Scholar
14 Imes, P. L.; Rhodes, P. H. U.S. Pat. 3,321,424, ( 1967).
Google Scholar
15 Zovko, M.; Barbariç, M.; Zorc, B.; Hafner, A.; Filipoviç Grçiç, J. Acta Pharm 2005, 55, 169.
CAS PubMed Google Scholar
16 Galioğlu Atici, O.; Akar, A.; Rahimian, R. Turk J Chem 2001, 25, 259.
Google Scholar
17 Wang, T.-L.; Lee, H.-M.; Kuo, P.-L. J Appl Polym Sci 2000, 78, 592.
10.1002/1097-4628(20001017)78:3<592::AID-APP140>3.0.CO;2-U
CAS Web of Science® Google Scholar
18 Hodge, P.; Davis, F.; Tredgold, R. H.; Silver, J.; Coles, H. J. Phil Trans R Soc Lond A 1990, 330, 153.
10.1098/rsta.1990.0009
CAS Web of Science® Google Scholar
19 Thompson, J. E. U.S. Pat. 6,719,053, ( 2004).
Google Scholar
20 Sartomer Company Inc.Product Catalog: SMA^® Multi-Functional Resins, Technical Literature 3100, 502 Thomas Jones Way, Exton, PA 19341.
Google Scholar
21 Cayli, G.; Kusefoglu, S. Fuel Process Technol 2008, 89, 118.
10.1016/j.fuproc.2007.06.020
CAS Web of Science® Google Scholar
22 Bunker, S. P.; Wool, R. P. J Polym Sci Part A: Polym Chem 2002, 40, 451.
10.1002/pola.10130
CAS Web of Science® Google Scholar
23 Badulescu, R.; Bolocan, I.; Vasilescu, D. S. Rev Roumaine Chem 2008, 53, 489.
CAS Web of Science® Google Scholar
24 Martínez, F.; Uribe, E.; Olea, A. F. J Macromol Sci Part A: Pure Appl Chem 2005, 42, 1063.
10.1081/MA-200065932
CAS Web of Science® Google Scholar
25 Shaghaghi, S.; Mahdavian, A. R. J Polym Res 2006, 13, 413.
10.1007/s10965-006-9061-y
CAS Web of Science® Google Scholar

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Volume116, Issue1

5 April 2010

Pages 355-365

New polymers from plant oil derivatives and styrene-maleic anhydride copolymers

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New polymers from plant oil derivatives and styrene-maleic anhydride copolymers

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