Miscibility and specific interactions in blends of poly(vinyl phenyl ketone hydrogenated) with poly(2,6-dimethyl-1,4-phenylene oxide)
M. Maldonado-Santoyo
Departamento de Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, Guadalajara, Jal. 44430, Mexico
Search for more papers by this authorCorresponding Author
S. M. Nuño-Donlucas
Departamento de Ingeniería Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, Guadalajara, Jal. 44430, Mexico
Departamento de Ingeniería Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, Guadalajara, Jal. 44430, Mexico===Search for more papers by this authorL. C. Cesteros
Grupo de Nuevos Materiales, Departamento de Química Física, Facultad de Ciencias, Campus de Leioa, Universidad del País Vasco, Apartado 644, Bilbao 48990, Spain
Search for more papers by this authorI. Katime
Grupo de Nuevos Materiales, Departamento de Química Física, Facultad de Ciencias, Campus de Leioa, Universidad del País Vasco, Apartado 644, Bilbao 48990, Spain
Search for more papers by this authorM. Maldonado-Santoyo
Departamento de Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, Guadalajara, Jal. 44430, Mexico
Search for more papers by this authorCorresponding Author
S. M. Nuño-Donlucas
Departamento de Ingeniería Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, Guadalajara, Jal. 44430, Mexico
Departamento de Ingeniería Química, Universidad de Guadalajara, Boulevard M. García Barragán 1451, Guadalajara, Jal. 44430, Mexico===Search for more papers by this authorL. C. Cesteros
Grupo de Nuevos Materiales, Departamento de Química Física, Facultad de Ciencias, Campus de Leioa, Universidad del País Vasco, Apartado 644, Bilbao 48990, Spain
Search for more papers by this authorI. Katime
Grupo de Nuevos Materiales, Departamento de Química Física, Facultad de Ciencias, Campus de Leioa, Universidad del País Vasco, Apartado 644, Bilbao 48990, Spain
Search for more papers by this authorAbstract
The miscibility behavior of poly(vinyl phenyl ketone hydrogenated) (PVPhKH) and poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) are studied by differential scanning calorimetry, thermomechanical analysis, and FTIR spectroscopy. Two miscibility windows between 10 to 40 and 60 to 90 wt % PPO are detected. Only the blend with 50 wt % PPO is immiscible. The best fit of the Gordon–Taylor equation of the experimental glass-transition temperatures for miscible PVPhKH/PPO blends is shown. A study by FTIR spectroscopy suggests that hydrogen bonding interactions are formed between the hydroxyl groups of PVPhKH and the ether groups of PPO. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1887–1892, 2004
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