RESEARCH ARTICLE
Efficient removal of emerging pollutant oxytetracycline by cost-effective biochar–hydroxyapatite composite
Quang Minh Tran,
Phuong Thu Le,
Thu Phuong Nguyen,
Hong Nam Nguyen,
Thi Hai Do,
Trung Dung Nguyen,
Thi Mai Thanh Dinh,
Quang Minh Tran
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Search for more papers by this authorCorresponding Author
Phuong Thu Le
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Correspondence
Phuong Thu Le and Thi Mai Thanh Dinh, University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam.
Emails: Email: [email protected] and
Email: [email protected]
Search for more papers by this authorThu Phuong Nguyen
Institute for Tropical Technology, A13 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Search for more papers by this authorHong Nam Nguyen
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Search for more papers by this authorThi Hai Do
Hanoi University of Mining and Geology, No.18 Vien Street, Duc Thang Ward, Bac Tu Liem District, Hanoi, Vietnam
Search for more papers by this authorTrung Dung Nguyen
Le Quy Don Technical University, 236 Hoang Quoc Viet, Hanoi, Vietnam
Search for more papers by this authorCorresponding Author
Thi Mai Thanh Dinh
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Correspondence
Phuong Thu Le and Thi Mai Thanh Dinh, University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam.
Emails: Email: [email protected] and
Email: [email protected]
Search for more papers by this authorQuang Minh Tran,
Phuong Thu Le,
Thu Phuong Nguyen,
Hong Nam Nguyen,
Thi Hai Do,
Trung Dung Nguyen,
Thi Mai Thanh Dinh,
Quang Minh Tran
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Search for more papers by this authorCorresponding Author
Phuong Thu Le
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Correspondence
Phuong Thu Le and Thi Mai Thanh Dinh, University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam.
Emails: Email: [email protected] and
Email: [email protected]
Search for more papers by this authorThu Phuong Nguyen
Institute for Tropical Technology, A13 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Search for more papers by this authorHong Nam Nguyen
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Search for more papers by this authorThi Hai Do
Hanoi University of Mining and Geology, No.18 Vien Street, Duc Thang Ward, Bac Tu Liem District, Hanoi, Vietnam
Search for more papers by this authorTrung Dung Nguyen
Le Quy Don Technical University, 236 Hoang Quoc Viet, Hanoi, Vietnam
Search for more papers by this authorCorresponding Author
Thi Mai Thanh Dinh
University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Correspondence
Phuong Thu Le and Thi Mai Thanh Dinh, University of Science and Technology of Hanoi, A21 Building, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam.
Emails: Email: [email protected] and
Email: [email protected]
Search for more papers by this authorAbstract
Biochar (BC) and hydroxyapatite (HAp) are widely used in environmental remediation due to their high adsorption capacity, porous structure, large specific surface area, chemical stability, non-toxicity, and low solubility. Combining BC and HAp is a green and effective strategy for creating new adsorbents (BCH) that have a synergistic impact on wastewater treatment. In this study, BCH composites derived from apatite ore and macadamia nut shells were synthesized by the wet impregnation method to remove oxytetracycline (OTC) from aqueous solutions. The BC-HAp composite with a ratio of 10:1 (by weight) was the most effective material for removing OTC. The Redlich–Peterson model achieved the highest correlation coefficient among the four models tested (Freundlich, Langmuir, Temkin, and Redlich–Peterson). The maximum adsorption capacity calculated with the Langmuir isotherm was 49.59 mg g−1. It was found that the adsorption process was significantly affected by the solution pH. The bipolar form of the drug was found to be OTC±, and the adsorption was most effective in solutions with a pH of 6. The OTC adsorption dominant mechanisms on nanocomposites could be electrostatic attraction, hydrogen bonding formation, surface complexation, or ion exchange. Therefore, the BCH composite showed great potential for removing OTC pollutants in a cost-effective, and environmentally friendly manner.
CONFLICT OF INTEREST STATEMENT
The authors declare no conflicts of interest.
Open Research
DATA AVAILABILITY STATEMENT
Data will be made available on request.
Supporting Information
| Filename | Description |
|---|---|
| apj3124-sup-0001-Figure_S1.docxWord 2007 document , 40.7 KB |
Fig. S1 (a) UV–vis spectra and (b) calibration curve of OTC. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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