Copper nanoparticles supported on 2-methoxy-1-phenylethanone-functionalized MCM-41: An efficient and recyclable catalyst for one-pot three-component C–S coupling reaction of aryl halides with benzyl bromide and thiourea
Corresponding Author
Abdol R. Hajipour
Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan, University of Technology, Isfahan, 84156 Islamic Republic of Iran
Department of Pharmacology, University of Wisconsin, Medical School, 1300 University, Avenue, Madison, 53706-1532 WI, USA
College of Pardis, Chemistry Section, Isfahan University of Technology, Isfahan, 84156-83111 Islamic Republic of Iran
Correspondence
Abdol R. Hajipour, Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, IR Iran.
Email: [email protected]
Search for more papers by this authorFarzaneh Fakhari
College of Pardis, Chemistry Section, Isfahan University of Technology, Isfahan, 84156-83111 Islamic Republic of Iran
Search for more papers by this authorGholamreza Nabi Bidhendi
Faculty of Environment, University of Tehran, Azin Avenue, Ghods Street, Enghelab Square, Tehran, Islamic Republic of Iran
Search for more papers by this authorCorresponding Author
Abdol R. Hajipour
Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan, University of Technology, Isfahan, 84156 Islamic Republic of Iran
Department of Pharmacology, University of Wisconsin, Medical School, 1300 University, Avenue, Madison, 53706-1532 WI, USA
College of Pardis, Chemistry Section, Isfahan University of Technology, Isfahan, 84156-83111 Islamic Republic of Iran
Correspondence
Abdol R. Hajipour, Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, IR Iran.
Email: [email protected]
Search for more papers by this authorFarzaneh Fakhari
College of Pardis, Chemistry Section, Isfahan University of Technology, Isfahan, 84156-83111 Islamic Republic of Iran
Search for more papers by this authorGholamreza Nabi Bidhendi
Faculty of Environment, University of Tehran, Azin Avenue, Ghods Street, Enghelab Square, Tehran, Islamic Republic of Iran
Search for more papers by this authorAbstract
An environmentally friendly copper-based catalyst supported on 2-methoxy-1-phenylethanone-functionalized MCM-41 was prepared and characterized by Fourier transform-infrared, transmission electron microscopy, field emission-scanning electron microscopy, X-ray diffraction and inductively coupled plasma techniques. The catalyst was applied for the one-pot three-component C–S coupling reactions of aryl halides with benzyl bromide and thiourea under aerobic conditions to afford the corresponding coupled products in good yields in water. The catalyst could be recovered and recycled five times. These results prove 2-methoxy-1-phenylethanone-functionalized MCM-41 supported Cu (II) complex was not leached during the reaction. Also it shows the correct heterogeneous nature of the catalyst.
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