Applications of transition metal complexes containing aminophosphine ligand to transfer hydrogenation of ketones
Corresponding Author
Murat Aydemir
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey.Search for more papers by this authorAkın Baysal
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey
Search for more papers by this authorYılmaz Turgut
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey
Search for more papers by this authorCorresponding Author
Murat Aydemir
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey.Search for more papers by this authorAkın Baysal
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey
Search for more papers by this authorYılmaz Turgut
Dicle University, Department of Chemistry, TR-21280 Diyarbakır, Turkey
Search for more papers by this authorAbstract
Hydrogen transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. Reaction of [Ph2PNHCH2-C4H3S] with [Ru(η6-benzene)(µ-Cl)Cl]2, [Rh(µ-Cl)(cod)]2 and [Ir(η5-C5Me5)(µ-Cl)Cl]2 gave a range of new monodendate complexes [Ru(Ph2PNHCH2-C4H3S)(η6-benzene)Cl2], 1, [Rh(Ph2PNHCH2-C4H3S)(cod)Cl], 2, and [Ir(Ph2PNHCH2-C4H3S)(η5-C5Me5)Cl2], 3, respectively. All new complexes were fully characterized by analytical and spectroscopic methods. 1H31P NMR, 1H13C HETCOR or 1H1H COSY correlation experiments were used to confirm the spectral assignments. 1–3 are suitable catalyst precursors for the transfer hydrogenation of acetophenone derivatives. Notably [Ru(Ph2PNHCH2-C4H3S)(η6-benzene)Cl2], 1, acts as an excellent catalyst, giving the corresponding alcohols in 98–99% yields in 30 min at 82 °C (TOF ≤200 h−1) for the transfer hydrogenation reaction in comparison to analogous rhodium or iridium complexes. This transfer hydrogenation is characterized by low reversibility under these conditions. Copyright © 2011 John Wiley & Sons, Ltd.
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