Domino Catalysis: Palladium-Catalyzed Carbonylation of Allylic Alcohols to β,γ-Unsaturated Esters†
Dr. Qiang Liu
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorLipeng Wu
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorDr. Haijun Jiao
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorXianjie Fang
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorDr. Ralf Jackstell
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Matthias Beller
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)Search for more papers by this authorDr. Qiang Liu
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorLipeng Wu
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorDr. Haijun Jiao
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorXianjie Fang
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorDr. Ralf Jackstell
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Matthias Beller
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany)Search for more papers by this authorThe research has been funded by the State of Mecklenburg-Western Pomerania, the BMBF, and the DFG (Leibniz Prize). We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Koch, and S. Rossmeisl (all at LIKAT) for their excellent technical and analytical support. Q.L. thanks the Alexander von Humboldt Foundation for financial support.
Graphical Abstract
Make it green: The Pd-catalyzed carbonylation of allylic alcohols with aliphatic alcohols represents a cost-effective, salt-free, and atom-economic carbonylation process generating water as the sole by-product. Mechanistic studies uncovered a new domino CO coupling/carbonylation reaction pathway.
Supporting Information
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