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Low-Temperature Oxidation of Ethylene over Platinum Nanoparticles Supported on Mesoporous Silica^†

M. Sc. Chuanxia Jiang

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)

Graduate School of Chemical Sciences and Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628 (Japan)

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Dr. Kenji Hara,

Dr. Kenji Hara

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)

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Prof. Dr. Atsushi Fukuoka,

Corresponding Author

Prof. Dr. Atsushi Fukuoka

[email protected]

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)Search for more papers by this author

M. Sc. Chuanxia Jiang,

M. Sc. Chuanxia Jiang

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)

Graduate School of Chemical Sciences and Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628 (Japan)

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Dr. Kenji Hara,

Dr. Kenji Hara

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)

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Prof. Dr. Atsushi Fukuoka,

Corresponding Author

Prof. Dr. Atsushi Fukuoka

[email protected]

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)

Catalysis Research Center, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021 (Japan)Search for more papers by this author

First published: 03 May 2013

https://doi.org/10.1002/anie.201300496

Citations: 99

^†

C.X.J. acknowledges MEXT of Japan for a scholarship.

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Graphical Abstract

Fresh fruit not rotting vegetables: Ethylene released from fruits and vegetables accelerates their spoiling even in refrigerators. To oxidatively remove traces of ethylene from a gas mix, supported metal nanoparticles were tested. A Pt catalyst supported on mesoporous silica gave complete conversion of 50 ppm ethylene even at 0 °C. IR experiments suggest the facile oxidation of CO over Pt on the silica supports is the key to the catalytic activity.

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Volume52, Issue24

June 10, 2013

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Low-Temperature Oxidation of Ethylene over Platinum Nanoparticles Supported on Mesoporous Silica^†

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Low-Temperature Oxidation of Ethylene over Platinum Nanoparticles Supported on Mesoporous Silica^†