A Self-Assembled Multiporphyrin Cage Complex through Three Different Zinc(II) Center Formation under Well-Balanced Aqueous Conditions†
Takashi Nakamura
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorDr. Hitoshi Ube
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorDr. Motoo Shiro
Rigaku Corporation, 3-9-12 Matsubaracho, Akishima, Tokyo 196-8666 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Mitsuhiko Shionoya
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)Search for more papers by this authorTakashi Nakamura
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorDr. Hitoshi Ube
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorDr. Motoo Shiro
Rigaku Corporation, 3-9-12 Matsubaracho, Akishima, Tokyo 196-8666 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Mitsuhiko Shionoya
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)Search for more papers by this authorThis research was supported by Global COE Program and KAKENHI from the Japan Society for the Promotion of Science (JSPS) and MEXT (Japan). T. Nakamura thanks JSPS Research Fellowship for Young Scientists.
Graphical Abstract
Construction of a self-assembled cage complex through three different ZnII centers is achieved using a Zn porphyrin ligand with four 2,2′-bipyridin-5-yl (bpy) groups. The multiporphyrin cage encapsulates guest molecules unsymmetrically by π–π interactions. Well-balanced aqueous conditions, which allow the formation of both tris(bpy) and hydrated bis(bpy) ZnII units, result in the unsymmetrical yet well-defined supramolecular structure.
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