Hydrogen Production Coupled to Hydrocarbon Oxygenation from Photocatalytic Water Splitting†
Dr. Wangkheimayum Marjit Singh
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorDerek Pegram
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorHaifeng Duan
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorDr. Diganta Kalita
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorProf. Dr. Paul Simone
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorProf. Dr. Gary L. Emmert
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xuan Zhao
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)Search for more papers by this authorDr. Wangkheimayum Marjit Singh
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorDerek Pegram
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorHaifeng Duan
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorDr. Diganta Kalita
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorProf. Dr. Paul Simone
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorProf. Dr. Gary L. Emmert
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xuan Zhao
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)
Department of Chemistry, University of Memphis, Memphis, TN 38152 (USA)Search for more papers by this authorWe acknowledge the Department of Chemistry at The University of Memphis for support. We thank Prof. Theodore J. Burkey for helpful discussions and the NSF (grant number TN EPS 1004083) for support of Haifeng Duan.
Graphical Abstract
On the sunny side: A homogeneous system for H2 production and hydrocarbon oxidation was developed in the absence of any sacrificial reagent. This system consists of [Ru(TPA)(H2O)2]2+ and [Fe3(CO)12] as catalysts and [Ru(bpy)3]2+ and [Ir(bpy)(ppy)2]+ as photosensitizers (PS). Water is the oxygen source as well as the source for H2 formation (see picture; Sub=organic substrate).
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