Catalytic Degenerate and Nondegenerate Oxygen Atom Transfers Employing N2O and CO2 and a MII/MIV Cycle Mediated by Group 6 MIV Terminal Oxo Complexes†
Brendan L. Yonke
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Search for more papers by this authorJonathan P. Reeds
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Search for more papers by this authorPeter Y. Zavalij
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Search for more papers by this authorCorresponding Author
Prof. Lawrence R. Sita
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)Search for more papers by this authorBrendan L. Yonke
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Search for more papers by this authorJonathan P. Reeds
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Search for more papers by this authorPeter Y. Zavalij
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Search for more papers by this authorCorresponding Author
Prof. Lawrence R. Sita
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742 (USA)Search for more papers by this authorFunding for this work was provided by the Department of Energy, Basic Energy Sciences (DE-SC0002217). M=Mo, W.
Graphical Abstract
Green oxidation: A new class of Group 6 metal complexes catalyzes the direct oxidation of isocyanides through nondegenerate oxygen atom transfer (OAT) utilizing N2O as a chemical oxidant. In addition they serve as photocatalysts for the reversible degenerate OAT between CO and CO2 (see scheme).
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
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